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Record W4200301341 · doi:10.53063/synsint.2021.1468

Hydrogen evolution via noble metals based photocatalysts: A review

2021· review· en· W4200301341 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

venuePublished in a venue whose home country is Canada.
no affNo Canadian affiliation: this work is invisible to an affiliation-only frame.
No Canadian affiliation. An affiliation-only frame, the usual design, would never have seen this work. It is one of the works that make the case for inverting the frame.

Bibliographic record

VenueSynthesis and Sintering · 2021
Typereview
Languageen
FieldEnergy
TopicAdvanced Photocatalysis Techniques
Canadian institutionsnot available
Fundersnot available
KeywordsNoble metalPhotocatalysisCharge carrierNanotechnologyHydrogen productionMaterials scienceEnergy carrierHydrogenChemistryCatalysisMetalOptoelectronics

Abstract

fetched live from OpenAlex

In recent decades, the use of photocatalysts in the evolution of hydrogen (H2) has received much attention. However, the use of the well-known titanium oxide and another photocatalyst as a base for noble metals is limited due to their major weakness in electron-hole pair separation. The use of cocatalysts can be a good way to overcome this problem and provide better performance for the evolution of hydrogen. In this review, suitable high-efficiency cocatalysts for solar hydrogen production have been thoroughly reviewed. New strategies and solutions were examined in terms of increasing the recombination of charge carriers, designing reactive sites, and enhancing the wavelengths of light absorption. Several new types of cocatalysts based on semiconductors in noble groups and dual metals have been evaluated. It is expected that these photocatalysts will be able to reduce the activation energy of reaction and charge separation. In this regard, the existing views and challenges in the field of photocatalysts are presented. The characteristics of monoatomic photocatalysts are reviewed in this manuscript and the latest advances in this field are summarized. Further, the future trends and upcoming research are also briefly discussed. Finally, this review presents noble metal-based photocatalysts for providing suitable photocatalysts on a larger scale and improving their applicability.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Other design · Consensus signal: none
GenreCandidate signal: Review · Consensus signal: Review
Teacher disagreement score0.951
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0010.001
Meta-epidemiology (broad)0.0030.001
Bibliometrics0.0000.001
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.035
GPT teacher head0.318
Teacher spread0.283 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it