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Record W4200351237 · doi:10.1002/cjce.24335

Prediction of the <scp>ASTM</scp> and <scp>TBP</scp> distillation curves and specific gravity distribution curve for fuels and petroleum fluids

2021· article· en· W4200351237 on OpenAlexvenueno aff
Pouya Hosseinifar, Hamidreza Shahverdi

Bibliographic record

VenueThe Canadian Journal of Chemical Engineering · 2021
Typearticle
Languageen
FieldEngineering
TopicPhase Equilibria and Thermodynamics
Canadian institutionsnot available
Fundersnot available
KeywordsDistillationFraction (chemistry)Specific gravityBoiling pointThermodynamicsPetroleum engineeringMathematicsChemistryGeologyChromatographyMineralogyPhysics

Abstract

fetched live from OpenAlex

Abstract A predictive approach called the six‐point method is developed to construct distillation curves of different petroleum fluids based on the information of six points of the distillation curve at volume percentages (5, 10, 30, 50, 70, and 90). Indeed, six diverse mathematical equations are developed, which establish relationships between the six mentioned distillation temperatures and physical properties ( and ) of petroleum fluids. Having predicted the six points, a third‐order polynomial curve can easily be fitted over these data. Accordingly, the six‐point method is well capable of predicting the distillation curve of both American Society for Testing and Materials (ASTM) D86 and true boiling point (TBP) data for any arbitrary petroleum fluid using only their physical properties. Two auxiliary relations are also presented to estimate the physical properties that may not be available for a petroleum fraction. These relations enable the model to receive pairs of () and () as input parameters, instead of (). A useful transfer function is also developed to convert the TBP curve predicted by the six‐point method to the specific gravity distribution curve. Furthermore, a new set of experimental data obtained from the distillation test is also presented in this work. The experiment has been performed on the petroleum cuts resulting from the crude oil atmospheric distillation unit and Linear Alkyl Benzene (LAB) production unit. The model performance was carefully evaluated against a wide range of literature data as well as new experimental data provided in this study, and the mean of average absolute deviations (AAD%) values was 1.98% for about 233 samples, including 2039 data points.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.692
Threshold uncertainty score0.427

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.009
GPT teacher head0.177
Teacher spread0.168 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations12
Published2021
Admission routes1
Has abstractyes

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