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Record W4205342258 · doi:10.26434/chemrxiv-2022-kx69l

A biomembrane grown in situ for improved microfluidic microbial fuel cell performance using a pure culture Geobacter sulfurreducens electroactive biofilm

2022· preprint· en· W4205342258 on OpenAlexafffund
Lingling Gong, Mehran Abbaszadeh Amirdehi, Jayesh M. Sonawane, Nan Jia, Leon Torres de Oliveira, Jesse Greener

Bibliographic record

VenueChemRxiv · 2022
Typepreprint
Languageen
FieldEnvironmental Science
TopicMicrobial Fuel Cells and Bioremediation
Canadian institutionsUniversité Laval
FundersNatural Sciences and Engineering Research Council of CanadaCanada First Research Excellence FundChina Scholarship Council
KeywordsMicrobial fuel cellMicrofluidicsMaterials scienceMembraneGeobacter sulfurreducensAnodeInternal resistanceElectrodeChemical engineeringGeobacterCathodeNanotechnologyPower densityAnalytical Chemistry (journal)ChemistryBiofilmChromatographyPower (physics)Battery (electricity)Biology

Abstract

fetched live from OpenAlex

Microfluidic microbial fuel cells (MFCs) hold great potential to reproduce core functions of bulk MFCs for study and optimization under precise conditions. Unlike most MFC types, those in a microfluidic format typically do not use a membrane to separate anode and cathode compartments, relying instead on the physics of laminar flow to maintain isolation of independent liquid streams. This lowers cost, device complexity, and should reduce internal resistance. However, to avoid solution crossover, which is likely to occur due to inevitable instabilities during long operational times, authors often separate electrodes by distances of several millimeters or more. This reverses benefits on internal resistance, undermining a prime advantage of microfluidic MFCs. This work demonstrates a facile method for the in-situ synthesis of a microscale membrane, supporting sub-milimeter electrode spacing. The membrane added only 68.5 Ω to the cell internal resistance and its synthesis resulted in no measurable changes to Rct at either electrode. However, the method to grow the membrane after device synthesis greatly reduced complexity in device fabrication. Overall, the reduced electrode spacing that was facilitated by the membrane lowered internal resistance from 25 k to 10 k and provide stable operation even under non-ideal flow conditions. Compared to a state-of-the-art membraneless MFC with 6 mm electrode spacing, the membrane MFC provided approximately 45% higher power density, 290% higher current density and 7 times higher acetate conversation efficiency. Membrane-enhanced flow stability also delivered continuous increases to power density with increased flow rate over baseline levels, rising to 30% higher for flow rate increases of 100 times.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.001
Threshold uncertainty score0.003

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.012
GPT teacher head0.218
Teacher spread0.206 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations2
Published2022
Admission routes2
Has abstractyes

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