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Record W4205843204 · doi:10.1002/cmtd.202100102

Cover Picture: Pressurized Sample Infusion (Chem. Methods 1/2022)

2022· paratext· en· W4205843204 on OpenAlexaff
Gilian T. Thomas, Sofia Donnecke, Ian C. Chagunda, J. Scott McIndoe

Bibliographic record

VenueChemistry - Methods · 2022
Typeparatext
Languageen
FieldChemistry
TopicMass Spectrometry Techniques and Applications
Canadian institutionsUniversity of Victoria
Fundersnot available
KeywordsMass spectrometryIonElectrospray ionizationFront coverAnalytical Chemistry (journal)KineticsChemistryCover (algebra)IonizationChromatographyOrganic chemistryPhysics

Abstract

fetched live from OpenAlex

The Front Cover shows a pressurized reaction vessel with tubing leading out of the flask. That tubing normally leads directly into an electrospray ionization mass spectrometer, where the mass-to-charge ratio and relative abundance of the solution phase ions are measured. These data can be used to generate chronograms for each solution species, shown here in the form of a reactant diminishing with first order kinetics, accompanied by the formation of a product ion. More information can be found in the Review by Gilian T. Thomas et al.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.002
metaresearch head score (Gemma)0.001
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow), Research integrity, Insufficient payload (model declined to judge)
Consensus categoriesResearch integrity
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: none
GenreCandidate signal: Other · Consensus signal: none
Teacher disagreement score0.784
Threshold uncertainty score0.999

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0020.001
Meta-epidemiology (narrow)0.0010.001
Meta-epidemiology (broad)0.0020.001
Bibliometrics0.0000.001
Science and technology studies0.0010.000
Scholarly communication0.0000.000
Open science0.0020.002
Research integrity0.0020.004
Insufficient payload (model declined to judge)0.7840.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.029
GPT teacher head0.391
Teacher spread0.362 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; both teacher heads agree on what is shown here.

Study designBench or experimental
Domainnot available
GenreOther

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2022
Admission routes1
Has abstractyes

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