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Record W4206660088 · doi:10.1002/cjce.24365

Two‐step thermal decomposition mechanism of phosphogypsum for resource utilization

2022· article· en· W4206660088 on OpenAlexvenueno aff
Wenmin Qian, Ping Ning, Haodong Zhu, Xin Song

Bibliographic record

VenueThe Canadian Journal of Chemical Engineering · 2022
Typearticle
Languageen
FieldEarth and Planetary Sciences
TopicCoal and Its By-products
Canadian institutionsnot available
FundersNational Key Research and Development Program of ChinaNational Natural Science Foundation of China
KeywordsPhosphogypsumOxidizing agentDecompositionThermal decompositionChemical process of decompositionAnhydrousChemistryReducing agentProcess (computing)Organic chemistry

Abstract

fetched live from OpenAlex

Abstract In this work, the reduction–oxidation two‐step method was used for investigating the resource utilization of phosphogypsum. The influences of different decomposition conditions were investigated, including the reducing process and oxidizing process. The reductive organic sulphide in lignite reacted with CaSO 4 and improved the CaSO 4 decomposition rate. High Fe 2 (SO 4 ) 3 content and anhydrous air flow rate promoted the formation of Fe–Ca–Ox, decreasing the CaSO 4 decomposition rate. H 2 O derived from CH 4 reacted with lignite to consume the solid reducing agent. In the reducing process, CaSO 4 reacted with CH 4 and lignite to form CO, CO 2 , H 2 O, and CaS. In the oxidizing process, CaS was mainly oxidized into CaO, SO 2 , and element S. Through a two‐step decomposition process (reduction with CH 4 and oxidation with air), the decomposition temperature of phosphogypsum decreases and the decomposition efficiency is improved. Meanwhile, the residual lignite was oxidized into CO and CO 2 . Therefore, it is meaningful and valuable.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Simulation or modeling · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.315
Threshold uncertainty score0.311

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.014
GPT teacher head0.189
Teacher spread0.176 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designSimulation or modeling
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations8
Published2022
Admission routes1
Has abstractyes

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