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Record W4207002636 · doi:10.1002/047084289x.rn02313

<i>p</i> ‐Nitrobenzenesulfonylhydrazine

2022· other· en· W4207002636 on OpenAlexaff
Kévin Saint‐Jacques

Bibliographic record

VenueEncyclopedia of Reagents for Organic Synthesis · 2022
Typeother
Languageen
FieldChemistry
TopicSulfur-Based Synthesis Techniques
Canadian institutionsUniversité de Montréal
Fundersnot available
KeywordsReagentHydrazine (antidepressant)HydrazoneChemistrySolubilitySulfonic acidChlorideMedicinal chemistrySulfonylNuclear chemistryOrganic chemistryCombinatorial chemistryChromatography

Abstract

fetched live from OpenAlex

[2937-05-5] C6H7N3O4S (MW 217.21) InChI = 1S/C6H7N3O4S/c7-8-14(12,13)6-3-1-5(2-4-6)9(10)11/h1-4,8H,7H2 InChIKey = QSFQGKRLZCXSPE-UHFFFAOYSA-N (reagent for the synthesis of sulfonyl hydrazone and N-heterocycles and CC, CN, CS, NS, and SS bond formation) Physical Data: mp 150–152 °C.1 Solubility: DMSO, THF; insoluble in water, Et2O, and hexanes.2 Form Supplied in: white solid; not commercially available. Preparative Method: the title reagent can be prepared from 4-nitrobenzenesulfonyl chloride and hydrazine monohydrate in a water/THF mixture2 or in two steps from sulfonic acid and CDI and then hydrazine monohydrate heated in MeCN.3 Purification: suspended in Et2O and filtered.2 Handling, Storage, and Precautions: no specific precaution.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.002
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow), Insufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Not applicable · Consensus signal: Not applicable
GenreCandidate signal: Other · Consensus signal: Other
Teacher disagreement score0.359
Threshold uncertainty score0.999

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.002
Meta-epidemiology (narrow)0.0010.001
Meta-epidemiology (broad)0.0010.001
Bibliometrics0.0010.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0020.000
Research integrity0.0010.000
Insufficient payload (model declined to judge)0.3590.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.009
GPT teacher head0.231
Teacher spread0.222 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designNot applicable
Domainnot available
GenreOther

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2022
Admission routes1
Has abstractyes

Explore more

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