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Record W4210415480 · doi:10.26434/chemrxiv-2021-f1zvq

Water-mediated adhesion of oil sands on solid surfaces at low temperature

2021· preprint· en· W4210415480 on OpenAlexafffund
Qimeng Yang, Jae Bem You, Boran Tian, Shaofeng Sun, Dan Daniel, Qi Liu, Xuehua Zhang

Bibliographic record

VenueChemRxiv · 2021
Typepreprint
Languageen
FieldMaterials Science
TopicSurface Modification and Superhydrophobicity
Canadian institutionsImperial Oil (Canada)University of Alberta
FundersNatural Sciences and Engineering Research Council of CanadaUniversity of AlbertaInstitute for Oil Sands Innovation, University of AlbertaImperial Oil Limited
KeywordsAdhesionAsphaltMaterials scienceSubstrate (aquarium)Capillary actionOil sandsFoulingContact angleSurface energyComposite materialChemical engineeringChemistryGeologyMembrane

Abstract

fetched live from OpenAlex

Adhesion of frozen granular materials on solid surfaces creates various problems for surface cleaning, reduces the carrying capacity of vehicles, and increases energy consumption for in-land transportation. Here we report that water content determines the adhesion strength of oil sands on solid surfaces at temperature of -2.5 ◦C to -20 ◦C. Our measurements by X-ray micro-computed tomography revealed that water forms capillary bridges between the sand particles and the solid substrate and more air gaps at the interface between oil sands and the substrate are filled with interstitial water at a higher content. We experimentally measured the minimal force required to push the frozen oil sands off the substrate and identified that the adhesion strength increased linearly with water content from 4% to 14% on both rubber and steel substrate. For short freezing time at a fixed water content, lowering the temperature increased the adhesion strength on the steel substrate. Fouling from a layer of bitumen or asphaltenes aggravated the adhesion of oil sands on steel. A theoretical model was proposed to rationalize the linear relationship between water content and the adhesion strength, based on the contact area between ice and the substrate. We also found an effective method to reduce the adhesion of oil sands by spraying a little amount of anti-freezing liquid on the substrate. Our approach may reduce the energy consumption in transport and processing of wet granular materials, and potentially save manpower and the cost from cleaning in industrial operations. The insight from our work may have wide applicability to many natural/industrial processes, such as soil formation, food processing, and porous structures in ice crystal-templating nanomaterials synthesis by freezing-drying.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow), Insufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.003
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0010.001
Research integrity0.0010.000
Insufficient payload (model declined to judge)0.0030.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.021
GPT teacher head0.251
Teacher spread0.230 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations3
Published2021
Admission routes2
Has abstractyes

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