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Chloroethylenes

2004· other· en· W4211201650 on OpenAlexaboutno aff
Gayle Snedecor, J. C. Hickman, James A. Mertens

Bibliographic record

VenueKirk-Othmer Encyclopedia of Chemical Technology · 2004
Typeother
Languageen
FieldEngineering
TopicCarbon Dioxide Capture Technologies
Canadian institutionsnot available
Fundersnot available
KeywordsTrichloroethyleneTetrachloroethyleneDegreasingSolventEnvironmental chemistryChlorinated solventsChemistryChlorinated paraffinsCombustibilityFlammable liquidChemical industryOrganic chemistryWaste managementEnvironmental scienceContaminationEngineeringCombustion

Abstract

fetched live from OpenAlex

Abstract The physical and chemical properties, manufacturing methods, uses, environmental concerns, and toxicity of 1,2‐dichloroethane are discussed. 1,2‐Dichloroethylene, also known as acetylene dichloride, dio‐form, α,β ‐dichloroethylene, and sym ‐dichloroethylene, exists in two isomers cis[156‐59‐2] and trans[156‐59‐2]. This solvent is used as an extraction solvent and as a chemical intermediate for other chlorinated solvents and compounds. The article describes the manufacturing, chemical and physical properties, storage and handling, toxicity, and its common uses. Trichloroethylene, commonly referred to as “tri”, is a widely used vapor‐degreasing solvent. In recent years its popularity has fallen mostly because of environmental restrictions on its use. Trichloroethylene has excellent solvency properties for a large number of natural and synthetic substances. This article includes physical and chemical properties, production, and use information. In addition, safety, toxicological, and environmental regulations pertinent to trichloroethylene are reviewed. Tetrachloroethylene [127‐18‐4], perchloroethylene, tetrachloroethene, commonly referred to as “perc,” is widely used in the dry‐cleaning industry as well as metal cleaning and vapor degreasing because of its excellent solvent properties. It has no flash point or flammable limits in air or oxygen. This article includes the physical and chemical properties of tetrachloroethylene, historical production within the United States, manufacturing locations and processes, as well as typical quality specifications. In addition, safety and toxicological considerations and environmental regulations pertinent to tetrachloroethylene are reviewed. The Montreal Protocol has had an impact on all of the compounds discussed in this article.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow), Research integrity
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Not applicable · Consensus signal: Not applicable
GenreCandidate signal: Other · Consensus signal: none
Teacher disagreement score0.657
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0010.001
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0010.001
Science and technology studies0.0000.001
Scholarly communication0.0000.000
Open science0.0010.000
Research integrity0.0030.001
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.004
GPT teacher head0.196
Teacher spread0.193 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designNot applicable
Domainnot available
GenreOther

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2004
Admission routes1
Has abstractyes

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