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Record W4212910150 · doi:10.2533/chimia.2012.532

Inorganic & Coordination Chemistry: Abstracts 211-279

2012· article· en· W4212910150 on OpenAlexaff
Douglas W. Stephan, Maksym V. Kovalenko, Luciesägesser Andachim Ecker, Julie Risse, M.A. Fernandez-Zumel, Yanouk Cudré, Kay Severin, Stefan Knoppe, Igor Dolamic, Jaianand Garg, Alexander Szentkuti, Koushik Olivierblacque, Maurus Schmid, Thomas R. Ward, Markus Meuwly, Amos J. Rosenthal, Matthias Vogt, Bas de Bruin, Hansjörg Grützmacher

Bibliographic record

VenueCHIMIA International Journal for Chemistry · 2012
Typearticle
Languageen
FieldChemistry
TopicZeolite Catalysis and Synthesis
Canadian institutionsUniversity of Toronto
FundersÉcole Polytechnique Fédérale de Lausanne
KeywordsChemistryCoordination complexComputational biologyBiologyOrganic chemistry

Abstract

fetched live from OpenAlex

In an approach to design selectives olid catalysts we start fromt he knowledge,atthe molecularlevel,ofthe reactiontobecatalyzed.Thenhypothesisa re made on then atureo ft he actives itesr equired.A tt hisp oint we are readytosynthesizesolid materials, in where therequiredactivesitesare introduced as well definedentities. On topofthatthe adsorption propertiesof thesolid are taylored to optimizethe interactions between reactants, catalyst andproducts.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.001
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow), Insufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.272
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.001
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0010.000
Research integrity0.0000.001
Insufficient payload (model declined to judge)0.0120.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.021
GPT teacher head0.282
Teacher spread0.261 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2012
Admission routes1
Has abstractyes

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