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Record W4212972088 · doi:10.5194/bg-2021-189-rc1

Comment on bg-2021-189

2021· peer-review· en· W4212972088 on OpenAlexfundno aff

Bibliographic record

Venuenot available
Typepeer-review
Languageen
FieldEnvironmental Science
TopicAir Quality Monitoring and Forecasting
Canadian institutionsnot available
FundersNatural Sciences and Engineering Research Council of Canada
KeywordsDimethyl sulfideMesoscale meteorologyEnvironmental scienceSea surface temperatureSubarctic climateSatelliteClimatologyAtmospheric sciencesAerosolFlux (metallurgy)MeteorologyOceanographyGeologyChemistryGeography

Abstract

fetched live from OpenAlex

<strong class="journal-contentHeaderColor">Abstract.</strong> Dimethyl sulfide (DMS) is a volatile biogenic gas with the potential to influence regional climate as a source of atmospheric aerosols and cloud condensation nuclei (CCN). The complexity of the oceanic DMS cycle presents a challenge in accurately predicting sea-surface concentrations and sea-air fluxes of this gas. In this study, we applied machine learning methods to model the distribution of DMS in the NE Subarctic Pacific (NESAP), a global DMS hot-spot. Using nearly two decades of ship-based DMS observations, combined with satellite-derived oceanographic data, we constructed ensembles of 1000 machine-learning models using two techniques, random forest regression (RFR) and artificial neural networks (ANN). Our models dramatically improve upon existing statistical DMS models, capturing up to 62&thinsp;% of observed DMS variability in the NESAP and demonstrate notable regional patterns that are associated with mesoscale oceanographic variability. In particular, our results indicate a strong coherence between DMS concentrations, sea surface nitrate (SSN) concentrations, photosynthetically active radiation (PAR) and sea surface height anomalies (SSHA), suggesting that NESAP DMS cycling is primarily influenced by heterogenous nutrient availability, light-dependent processes and physical mixing. Based on our model output, we derive summertime, sea-air flux estimates ranging between 0.5&ndash;2.0&thinsp;Tg&thinsp;S&thinsp;yr<sup>&minus;1</sup> in the NESAP. Our work demonstrates a new approach to capturing spatial and temporal patterns in DMS variability, which is likely applicable to other oceanic regions.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesInsufficient payload (model declined to judge)
Consensus categoriesInsufficient payload (model declined to judge)
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Not applicable · Consensus signal: Not applicable
GenreCandidate signal: Other · Consensus signal: Other
Teacher disagreement score0.335
Threshold uncertainty score0.997

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0430.004

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.067
GPT teacher head0.323
Teacher spread0.256 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; both teacher heads agree on what is shown here.

Study designNot applicable
Domainnot available
GenreOther

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2021
Admission routes1
Has abstractyes

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