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Record W4213048552 · doi:10.53063/synsint.2022.21105

Molecular hydrogen production by radiolysis of water on the surface of nano-ZrO2 under the influence of gamma rays

2022· article· en· W4213048552 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

venuePublished in a venue whose home country is Canada.
no affNo Canadian affiliation: this work is invisible to an affiliation-only frame.
No Canadian affiliation. An affiliation-only frame, the usual design, would never have seen this work. It is one of the works that make the case for inverting the frame.

Bibliographic record

VenueSynthesis and Sintering · 2022
Typearticle
Languageen
FieldMaterials Science
TopicNuclear Materials and Properties
Canadian institutionsnot available
Fundersnot available
KeywordsRadiolysisDecompositionZirconium dioxideChemistryNanoparticleHydrogenKineticsHydrogen productionEnthalpyOxideChemical engineeringMaterials scienceRadicalNanotechnologyOrganic chemistryThermodynamics

Abstract

fetched live from OpenAlex

In this research, the radiation-heterogeneous processes of water decomposition on the surface of zirconium dioxide nanoparticles (n-ZrO2) were studied. The kinetics of buildup of molecular hydrogen during the radiolytic processes of water decomposition was also examined. The production of H2 and H2O2 through water radiolysis was investigated to develop a computational model and disclose the kinetic behavior of water radiolysis. The enthalpy of ZrO2 nanoparticles was studied at the temperature range T=1200-2900 K, in which ZrO2 nanoparticles has a two-phase transition. Some of the electrons were transported to the surface of the nanoparticles during the physical and physicochemical stages of the process and emitted into the water. At the same time, the migration of energy carriers in radioactively active oxide compounds changed at different intervals depending on the composition, structural stability, and electro-physical properties of the oxides.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.009
Threshold uncertainty score0.418

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.011
GPT teacher head0.189
Teacher spread0.179 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it