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Record W4214522122 · doi:10.1002/anie.200390452

Nanoporous Lanthanide–Copper(<scp>II</scp>) Coordination Polymers: Syntheses and Crystal Structures of [{M<sub>2</sub>(Cu<sub>3</sub>(iminodiacetate)<sub>6</sub>)}⋅8 H<sub>2</sub>O]<i><sub>n</sub></i> (M=La, Nd, Eu)

2003· article· en· W4214522122 on OpenAlexaboutno aff
Yan‐Ping Ren, La‐Sheng Long, Bing‐Wei Mao, Youzhu Yuan, Rong‐Bin Huang, Lan‐Sun Zheng

Bibliographic record

VenueAngewandte Chemie International Edition · 2003
Typearticle
Languageen
FieldChemistry
TopicMetal-Organic Frameworks: Synthesis and Applications
Canadian institutionsnot available
Fundersnot available
KeywordsLanthanideCopperCrystal structureCrystallographyChemistryMetalStereochemistryIonOrganic chemistry

Abstract

fetched live from OpenAlex

In the Communication “Nanoporous Lanthanide–Copper( II ) Coordination Polymers: Syntheses and Crystal Structures of [{M 2 (Cu 3 (iminodiacetate) 6 )}⋅8 H 2 O] n (M=La, Nd, Eu)” by Y.‐P. Ren, L.‐S. Long, et al. ( 1 ) the authors missed important references: “Synthesis, Crystal Structure and Magnetic Properties of a Series of Polymeric Lanthanoid–Copper Complexes [Ln 2 Cu 3 {O(CH 2 CO 2 ) 2 } 6 ]⋅ n H 2 O (Ln=La, Nd, n =9; Ln=Er, n =6)” (J. G. Mao, J. S. Huang, J. F. Ma, J. Z. Ni, Trans. Met. Chem. 1997 , 22 , 277–280), “Synthesis and Crystal Structure of a Novel Lanthanide–Copper Mixed Metal Complex: Gd 2 Cu 3 {O(CH 2 COO) 2 } 6 ⋅9 H 2 O” (J. G. Mao, L. Song, X. Y. Huang, J. S. Huang, Polyhedron 1997 , 16 , 963–966), “Synthesis and Structural Characterization of a Novel Polymeric Gadolinium( III )–Copper( II ) Complex of Iminodiacetic Acid” (J. G. Mao, L. Song, J. S. Huang, J. Chem. Crystallogr. 1998 , 28 , 475–479), and “Synthesis and Crystal Structure of a New Praseodymiun( III )–Copper( II ) Polymeric Complex: [Pr 2 (Cu 3 (L 1 ) 6 ) n ] (H 2 L 1 =NH{CH 2 COOH} 2 )” (J. G. Mao, L Song, J. S. Huang , Chinese J. Struct. Chem. 1999 , 18 , 4–8). The authors apologize for this oversight and thank Qinde Liu of Queen's University, Canada, and Prof. J. G. Mao, Fuzhou, China, for bringing it to their attention.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.003
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow), Research integrity
Consensus categoriesMeta-epidemiology (narrow)
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.023
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.003
Meta-epidemiology (narrow)0.0020.002
Meta-epidemiology (broad)0.0010.001
Bibliometrics0.0010.001
Science and technology studies0.0010.001
Scholarly communication0.0010.001
Open science0.0010.000
Research integrity0.0010.001
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.011
GPT teacher head0.222
Teacher spread0.211 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; both teacher heads agree on what is shown here.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations156
Published2003
Admission routes1
Has abstractyes

Explore more

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