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Record W4214912756 · doi:10.1002/anie.202117703

Hierarchically Nanostructured Solid‐State Electrolyte for Flexible Rechargeable Zinc–Air Batteries

2022· article· en· W4214912756 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.

Bibliographic record

VenueAngewandte Chemie International Edition · 2022
Typearticle
Languageen
FieldEngineering
TopicAdvanced battery technologies research
Canadian institutionsUniversity of Waterloo
Fundersnot available
KeywordsMaterials scienceElectrolyteQuasi-solidNanotechnologyPolymerizationIonic liquidHydroxideIonic conductivityNanofiberChemical engineeringPolymerComposite materialChemistryElectrode

Abstract

fetched live from OpenAlex

Abstract The construction of safe and environmentally‐benign solid‐state electrolytes (SSEs) with intrinsic hydroxide ion‐conduction for flexible zinc–air batteries is highly desirable yet extremely challenging. Herein, hierarchically nanostructured CCNF‐PDIL SSEs with reinforced concrete architecture are constructed by nanoconfined polymerization of dual‐cation ionic liquid (PDIL, concrete) within a robust three‐dimensional porous cationic cellulose nanofiber matrix (CCNF, reinforcing steel), where plenty of penetrating ion‐conductive channels are formed and undergo dynamic self‐rearrangement under different hydrated levels. The CCNF‐PDIL SSEs synchronously exhibit good flexibility, mechanical robustness, superhigh ion conductivity of 286.5 mS cm −1 , and decent water uptake. The resultant flexible solid‐state zinc–air batteries deliver a high‐power density of 135 mW cm −2 , a specific capacity of 775 mAh g −1 and an ultralong cycling stability with continuous operation of 240 hours for 720 cycles, far outperforming those of the state‐of‐the‐art solid‐state batteries. The marriage of biomaterials with the diversity of ionic liquids creates enormous opportunities to construct advanced SSEs for solid‐state batteries.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: none
Teacher disagreement score0.803
Threshold uncertainty score0.801

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.013
GPT teacher head0.268
Teacher spread0.255 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it