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Record W4220789343 · doi:10.5194/egusphere-egu22-9161

Enrichment of immobile elements in synmagmatic fractures

2022· preprint· en· W4220789343 on OpenAlexaff
Taylor Witcher, Steffi Burchardt, Michael J. Heap, Alexandra Kushnir, Anne Pluymakers, Tobias Schmiedel, Iain Pitcairn, Tobias Mattsson, Pim Kaskes, Philippe Claeys, Shaun L.L. Barker, C. Johan Lissenberg

Bibliographic record

Venuenot available
Typepreprint
Languageen
FieldEarth and Planetary Sciences
TopicGeochemistry and Elemental Analysis
Canadian institutionsUniversity of British Columbia
Fundersnot available
KeywordsGeologyGeochemistryMagmaMineralogyTexture (cosmology)CarbonateRhyoliteFracture (geology)MineralMaterials scienceVolcanoMetallurgyPaleontologyVolcanic rock

Abstract

fetched live from OpenAlex

Useful minerals containing rare Earth elements (REE) and metals are sourced from magma bodies, but exactly how these elements initially leave the magma is not well known. Here we present textural and chemical analyses of mineral-filled fracture bands within the rhyolitic Sandfell laccolith exposed in eastern Iceland. The fracture fillings showcase dynamic and complex textures and imply multiple energy levels during precipitation. The dominant mineral phases are Fe- and Mg-oxides, Mn carbonate, and La/Ce oxide. The textures they present are comb, laminate, radial, and a rounded reworked clastic texture filling the tips. Microtomography images of hand-samples show the fractures are stretched-penny shaped, and contain 80 vol% fillings and 20 vol% void space. The connectivity of fractures within one band is limited to 1-3 neighbours, via small oblique fractures joining two main fractures together. µXRF measurements revealed distinct halos of 0.8 wt% Fe depletion surrounding each facture, and within the fracture-fill a strong enrichment in an unusual suite of elements including Fe, Mn, Cl, Zn, Cr, Y, Ce, and La. This assemblage is puzzling, as many of these elements are typically carried by fluids which have strong alteration effects on the surrounding rock, and there is a lack of this kind of alteration at Sandfell. Our working hypothesis is that the formation of the fractures provided a degassing pathway through the impermeable magma. However, the nature and the composition of the magmatic volatiles are as yet unknown. The minimal connectivity between fractures (at hand-sample scale) suggests fluid would have travelled through the length of one to three fractures until intersecting with another fracture band system, and minerals precipitated along the way. Given the ubiquitous occurrence of the fracture bands within the laccolith, this small-scale process compounds into large amounts of mass transfer overall. The fractures at Sandfell may be a snapshot of the initial process of removing incompatible elements from silicic magma.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Observational · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.007
Threshold uncertainty score0.014

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0010.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.008
GPT teacher head0.242
Teacher spread0.234 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designObservational
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

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Citations0
Published2022
Admission routes1
Has abstractyes

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