Assessing the Versatility and Robustness of Pore Network Modeling to Simulate Redox Flow Battery Electrode Performance
Why this work is in the frame
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Bibliographic record
Abstract
Porous electrodes are core components that determine the performance of redox flow batteries. Thus, optimizing their microstructure is a powerful approach to reduce system costs. Here we present a pore network modeling framework that is microstructure and chemistry agnostic, iteratively solves transport equations in both half-cells, and utilizes a network-in-series approach to simulate the local transport phenomena within porous electrodes at a low computational cost. In this study, we critically assess the versatility and robustness of pore network models to enable the modeling of different electrode geometries and redox chemistries. To do so, the proposed model was validated with two commonly used carbon fiber-based electrodes (a paper and a cloth), by extracting topologically equivalent networks from X-ray tomograms, and evaluated for two model redox chemistries (an aqueous iron-based and a non-aqueous TEMPO-based electrolyte). We find that the modeling framework successfully captures the experimental performance of the non-aqueous electrolyte but is less accurate for the aqueous electrolyte which was attributed to incomplete wetting of the electrode surface in the conducted experiments. Furthermore, the validation reveals that care must be taken when extracting networks from the tomogram of the woven cloth electrode, which features a multiscale microstructure with threaded fiber bundles. Employing this pore network model, we elucidate structure-performance relationships by leveraging the performance profiles and the simulated local distributions of physical properties and finally, we deploy simulations to identify efficient operation envelopes.
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Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.001 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.001 | 0.000 |
| Research integrity | 0.000 | 0.001 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it