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Record W4221042328 · doi:10.1002/aelm.202101377

Comprehensive Study on High Purity Semiconducting Carbon Nanotube Extraction

2022· article· en· W4221042328 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.

Bibliographic record

VenueAdvanced Electronic Materials · 2022
Typearticle
Languageen
FieldMaterials Science
TopicCarbon Nanotubes in Composites
Canadian institutionsKinova (Canada)National Research Council Canada
FundersDefense Advanced Research Projects AgencyNational Science Foundation
KeywordsCarbon nanotubeMaterials scienceVery-large-scale integrationNanotechnologyTransistorVoltageElectrical engineeringComputer scienceEmbedded system

Abstract

fetched live from OpenAlex

Abstract Carbon nanotubes (CNTs) are a rapidly maturing emerging technology for next‐generation energy‐efficient digital Very‐Large‐Scale‐Integrated (VLSI) systems. However, a major remaining challenge facing CNT field‐effect transistors (CNFETs) are metallic CNTs, causing incorrect logic functionality and increased leakage power. As no CNT synthesis technique demonstrates a reliable path toward manufacturing 99.99% semiconducting CNTs (s‐CNT; required purity for VLSI systems), significant work focuses on solution‐based sorting of CNTs (selectively removing metallic CNTs post‐synthesis). Yet, there lacks both well‐controlled comparisons carefully optimizing key processing parameters simultaneously (CNT synthesis sources, polymer additive used for selective sorting, etc.), as well as statistically significant electrical transistor characterization sample sizes to form concrete conclusions. Here, >90 000 CNFETs (totaling >90 million CNTs) are fabricated and characterized to demonstrate the following key advances: 1) systematic exploration of the impact of different combinations of CNT synthesis sources and polymer additives on the electrical performance of transistors (analyzing on‐current, off‐current, on off ratio, and threshold voltage) to find the best combination, 2) how the optimization and choice of the CNT source can be decoupled from that of the polymer, and 3) an optimal CNT solution that achieves >99.99% s‐CNT purity using electrical measurements, meeting the requirement for VLSI systems.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow), Insufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.004
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0000.000
Science and technology studies0.0010.000
Scholarly communication0.0000.000
Open science0.0010.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0020.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.014
GPT teacher head0.282
Teacher spread0.268 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it