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Record W4221049462 · doi:10.1149/1945-7111/ac5c9b

Scalable Implementation of Recombination Catalyst Layers to Mitigate Gas Crossover in PEM Water Electrolyzers

2022· article· en· W4221049462 on OpenAlexaff
Andrea Stähler, Markus Stähler, Fabian Scheepers, Werner Lehnert, Marcelo Carmo

Bibliographic record

VenueJournal of The Electrochemical Society · 2022
Typearticle
Languageen
FieldEngineering
TopicFuel Cells and Related Materials
Canadian institutionsQueen's University
Fundersnot available
KeywordsAnodeMembrane electrode assemblyLayer (electronics)HydrogenMaterials scienceElectrolyteCoatingElectrolysis of waterMembraneCathodeNafionProton exchange membrane fuel cellElectrolysisChemical engineeringElectrodeChemistryNanotechnologyElectrochemistryOrganic chemistry

Abstract

fetched live from OpenAlex

Hydrogen permeation across the membrane is a critical safety hurdle within polymer electrolyte membrane (PEM) water electrolysis (WE). It is crucial to implement recombination catalysts into the membrane electrode assemblies (MEAs) for reducing hydrogen concentrations and allow the use of much thinner membrane architectures that allow high efficiency operation. Here we show how recombination catalyst layers can be fabricated into MEAs by using a scalable method. In subsequent slot-die coating steps, an electrically insulating and then a recombination layer (both 5 μ m thick) are applied directly to the anode. This three-layer system is then processed into a 5-layer MEA with a cathode and membrane using the decal process. The 5-layer MEA shows a reliable hydrogen reduction in the anode product gas for a wide-range of membrane thicknesses. The long-term stability of the recombination layer is shown for a 5-layer Nafion™ HP-MEA in comparison to a 3-layer MEA. Even after long-term operation, the MEA shows a safe hydrogen concentration reduction on the anode. Finally, the presented technique is used to produce 5-layer MEAs with active areas of 1056 cm 2 and 60 μ m membrane thicknesses. Measurements on reference MEAs show a successful scale-up, proving the technique to be applicable to all scales.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.003
Threshold uncertainty score0.234

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.003
GPT teacher head0.209
Teacher spread0.206 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations49
Published2022
Admission routes1
Has abstractyes

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