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Record W4221087947 · doi:10.1002/adfm.202113209

Three‐In‐One Alkylamine‐Tuned MoO<i><sub>x</sub></i> for Lab‐Scale to Real‐Life Aqueous Supercapacitors

2022· article· en· W4221087947 on OpenAlexafffund
Xu Han, Chongchong Wu, Hao Li, Yusheng Zhang, Wenping Sun, Baohua Jia, Ian D. Gates, Zihang Huang, Tianyi Ma

Bibliographic record

VenueAdvanced Functional Materials · 2022
Typearticle
Languageen
FieldMaterials Science
TopicSupercapacitor Materials and Fabrication
Canadian institutionsUniversity of Calgary
FundersLiaoning Revitalization Talents ProgramCanada First Research Excellence FundLiaoning UniversityNational Natural Science Foundation of ChinaState Government of VictoriaRMIT UniversityCommonwealth Scientific and Industrial Research OrganisationUniversity of Calgary
KeywordsSupercapacitorMaterials scienceCapacitanceAqueous solutionNanotechnologyEnergy storageElectrochemistryChemical engineeringElectrodePower (physics)ChemistryOrganic chemistry

Abstract

fetched live from OpenAlex

Abstract Aqueous supercapacitors show advantages of high safely, prolonged lifespan, and low cost, etc. but there have never been commercial market products, nor quantitative investigation of practical pouch devices of aqueous supercapacitors. Herein, to achieve their lab‐scale to real‐life manufacture, a unique MoO x for supercapacitor use is constructed by a hydrothermal and annealing strategy suitable for industrialization, which plays three key functions, including precisely adjusted interlayer spacing, conductive flexible graphite carbon and abundant oxygen vacancies. As a result, the as‐synthesized electrode yields an ultra‐high specific capacitance of 717 F g −1 at 1 A g −1 and ultra‐long cycling durability with no obvious capacitive loss even after 100 000 cycles. Realistically, the assembled asymmetric supercapacitor (MoO x ‐HDA‐3//MnO 2 ) exhibits extraordinary energy density of 78.2 Wh kg −1 , superior to many advanced supercapacitors reported to date. We have fabricated pouch devices, which can successfully run 3C products such as tablets and smartphones, and maintain stable electrochemical performance even after heavy strikes, fires, and pressures. Quantitative investigation results confirm that the pouch device delivers an excellent specific capacitance of 74.7 F g −1 and a high energy density of 41.5 Wh kg −1 . This work enhances the confidence of pushing aqueous supercapacitors to realistic energy storage market.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow), Insufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.008
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0000.000
Science and technology studies0.0010.000
Scholarly communication0.0000.001
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0020.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.022
GPT teacher head0.228
Teacher spread0.205 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations30
Published2022
Admission routes2
Has abstractyes

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