Improved prediction of dimethyl sulfide (DMS) distributions in the northeast subarctic Pacific using machine-learning algorithms
Bibliographic record
Abstract
Abstract. Dimethyl sulfide (DMS) is a volatile biogenic gas with the potential to influence regional climate as a source of atmospheric aerosols and cloud condensation nuclei (CCN). The complexity of the oceanic DMS cycle presents a challenge in accurately predicting sea surface concentrations and sea–air fluxes of this gas. In this study, we applied machine-learning methods to model the distribution of DMS in the northeast subarctic Pacific (NESAP), a global DMS hot spot. Using nearly two decades of ship-based DMS observations, combined with satellite-derived oceanographic data, we constructed ensembles of 1000 machine-learning models using two techniques: random forest regression (RFR) and artificial neural networks (ANN). Our models dramatically improve upon existing statistical DMS models, capturing up to 62 % of observed DMS variability in the NESAP and demonstrating notable regional patterns that are associated with mesoscale oceanographic variability. In particular, our results indicate a strong coherence between DMS concentrations, sea surface nitrate (SSN) concentrations, photosynthetically active radiation (PAR), and sea surface height anomalies (SSHA), suggesting that NESAP DMS cycling is primarily influenced by heterogenous nutrient availability, light-dependent processes and physical mixing. Based on our model output, we derive summertime, sea–air flux estimates of 1.16 ± 1.22 Tg S in the NESAP. Our work demonstrates a new approach to capturing spatial and temporal patterns in DMS variability, which is likely applicable to other oceanic regions.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.001 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.001 |
| Science and technology studies | 0.001 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.001 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".