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Record W4223457937 · doi:10.1021/acs.iecr.2c00388

Selective Extraction and Recovery of Gold from Complex Thiosulfate Pregnant Leach Liquor Using Cyphos IL 101

2022· article· en· W4223457937 on OpenAlexafffund
Harshit Mahandra, Fariborz Faraji, Atefeh Azizitorghabeh, Ahmad Ghahreman

Bibliographic record

VenueIndustrial & Engineering Chemistry Research · 2022
Typearticle
Languageen
FieldEngineering
TopicExtraction and Separation Processes
Canadian institutionsQueen's University
FundersNatural Sciences and Engineering Research Council of Canada
KeywordsStripping (fiber)ChemistryIonic liquidExtraction (chemistry)ThiosulfateThioureaCopperInorganic chemistryTolueneSolventNuclear chemistryChromatographySulfurCatalysisOrganic chemistryMaterials science

Abstract

fetched live from OpenAlex

For the first time, an ionic liquid, Cyphos IL 101, has been evaluated for the selective gold recovery from thiosulfate leachate of sulfidic gold ore by solvent extraction. The pregnant leach solution at pH 9.5 contained 2.4 mg/L gold, 55.85 mg/L copper, and 0.26 mg/L silver in thiosulfate medium. The speciation of different metals was studied and selective gold extraction over copper and silver was achieved utilizing 0.1 mol/L Cyphos IL 101 at A/O = 5. Different ionic liquid carriers were tried to dilute Cyphos IL 101, and toluene was found the best choice. The number of extraction stages for gold was theoretically determined based on the McCabe Thiele diagram constructed for extraction and was confirmed at A/O = 4 and A/O = 5 followed by counter-current extraction. The different stripping agents were used and the gold stripping from the loaded organic solution was done using 5% thiourea in 1% HCl solution. The McCabe Thiele diagram for stripping was drawn and the number of theoretical stages needed to achieve an effective stripping was identified. A phase ratio of A/O = 1 needed three stripping stages, which were confirmed by the counter-current stripping experiment. Overall, the study showed attractive results and opens the area for further research in the future.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.001
Threshold uncertainty score0.002

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.138
GPT teacher head0.344
Teacher spread0.205 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations17
Published2022
Admission routes2
Has abstractyes

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