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Record W4223893923 · doi:10.1088/1367-2630/ac6767

Quantitative laser-based x-ray fluorescence and particle-induced x-ray emission

2022· article· en· W4223893923 on OpenAlex
Frédéric Boivin, Simon Vallières, S. Fourmaux, S. Payeur, P. Antici

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.
fundA Canadian funder is recorded on the work.

Bibliographic record

VenueNew Journal of Physics · 2022
Typearticle
Languageen
FieldPhysics and Astronomy
TopicX-ray Spectroscopy and Fluorescence Analysis
Canadian institutionsUniversity of WaterlooInstitut National de la Recherche Scientifique
FundersFonds de recherche du Québec – Nature et technologiesNatural Sciences and Engineering Research Council of CanadaCanada Foundation for InnovationCompute Canada
KeywordsPhysicsX-ray fluorescenceX-rayLaserMass spectrometryAnalytical Chemistry (journal)SpectrometerBrassBronzeSpectroscopyParticle (ecology)Emission spectrumX-ray spectroscopyMetalFluorescenceOpticsSpectral lineMaterials scienceCopperChemistryMetallurgy

Abstract

fetched live from OpenAlex

Abstract In this work, we demonstrate the feasibility of quantitative laser-based x-ray fluorescence (XRF) combined with particle-induced x-ray emission (PIXE) (called XPIF for x-ray and particle-induced fluorescence) spectroscopy analysis for elemental composition in solid samples. A multi-hundred TW laser system accelerated protons and produced x-rays that were impinging on solid samples, inducing characteristic line emissions of the elements contained in the material. The x-ray yield obtained from the characteristic emissions for each element can be related to its mass concentration using both the thick PIXE and thick XRF formalism. This is performed by using of an iterative numerical procedure. We tested the validity of our method on three homogeneous metallic materials, stainless steel, bronze and brass. The mass proportions of these samples retrieved by our analysis (XPIF) is within the errors bars compared with a commercial energy dispersive x-ray spectrometer.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.067
Threshold uncertainty score0.636

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.021
GPT teacher head0.284
Teacher spread0.263 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it