Atomic Isolation and Anchoring of Commercial Pt/C Nanoparticles, a Promising Pathway for Durable PEMFCs
Bibliographic record
Abstract
This study examines the atomic confinement of commercial Pt/C electrocatalysts. While a high electrocatalytic activity for the oxygen reduction reaction is important for proton-exchange membrane fuel cell (PEMFC) performance, the high stability of the electrocatalyst is essential for real applications under harsh operating conditions. The demands necessitate the development of advanced electrocatalysts that are resistant to corrosion. A combination of diazonium chemistry with Cu electrodeposition permits the selective protection of the carbon surface of the commercial Pt/C to prevent corrosion while improving wettability and ionic transfer. The resulting electrocatalysts exhibit an exceptional ORR stability after accelerated stress testing (AST) with a 250% improvement in comparison with unprotected commercial Pt/C. This novel electrochemical pathway provides a much-needed boost to carbon-based catalytic supports, which still face several stability challenges in energy applications in a harsh environment.
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How this classification was reachedexpand
Full frame machine prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.
Distilled classifier scores by category (both heads)
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.001 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".