Spectroscopic properties of the low-lying states of the HeH radical
Bibliographic record
Abstract
Four lowest electronic states ( X2Σ+, A2Σ+, B2Π, and C2Σ+) of the HeH radical are investigated by performing high-precision ab initio calculations. Potential energy curves of HeH are calculated using the multireference configuration interaction method and the basis set of aug-cc-pV6Z. Additional Rydberg basis functions and the Pople correction are included in the calculations. The spectral parameters are evaluated and compared with literature data. The spin–orbit coupling effect of B2Π is taken into account by using the Breit–Pauli operator. Transition dipole moments between those four electronic states are also derived to obtain their emission spectra and radiative lifetimes. Radiative and predissociation lifetimes of several vibrational levels are also calculated, including the bound–continuum and bound–bound systems. Especially, the predissociation lifetimes are elaborated in detail. The results are in good agreement with the reported ones. Additionally, the emission spectra of bound A2Σ+, B2Π, and C2Σ+ states to continuum X2Σ+ state are simulated at different temperatures.
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How this classification was reachedexpand
Full frame machine prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.
Distilled classifier scores by category (both heads)
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.001 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.001 | 0.000 |
| Research integrity | 0.000 | 0.001 |
| Insufficient payload (model declined to judge) | 0.004 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".