Energy cascades in polaritonic systems with energetic disorder observed by ultrafast two-dimensional white-light spectroscopy
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Bibliographic record
Abstract
Abstract Exciton-polaritons are hybrid states formed when molecular excitons are strongly coupled to photons trapped in an optical cavity. These systems have many attractive properties, including large delocalization lengths, but questions regarding the role of energetic disorder remain unanswered. Here, we fabricate microcavities with two different layers of semiconducting carbon nanotubes as a way of controlling the energetic disorder and exploring its impact on energy transfer. Using ultrafast two-dimensional white-light spectroscopy, we observe a delayed growth of a cross peak between the upper- and lower-polariton states. Using Redfield theory, we assign the growth to cascading energy transfer down a manifold of new electronic states created by energetic disorder that is of comparable magnitude to the light-matter coupling. These results broaden our understanding of energy transfer dynamics in exciton-polariton systems beyond the Rabi contraction picture and enable control over how energy is transported in polaritonic systems.
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Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.001 | 0.000 |
| Meta-epidemiology (narrow) | 0.001 | 0.001 |
| Meta-epidemiology (broad) | 0.001 | 0.000 |
| Bibliometrics | 0.001 | 0.001 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.001 | 0.000 |
| Open science | 0.001 | 0.001 |
| Research integrity | 0.000 | 0.003 |
| Insufficient payload (model declined to judge) | 0.004 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it