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Record W4226066690 · doi:10.1038/s41561-022-00921-6

Fluocerite as a precursor to rare earth element fractionation in ore-forming systems

2022· article· en· W4226066690 on OpenAlexaff
Andrew Strzelecki, Artas Migdisov, Hakim Boukhalfa, Kirsten Sauer, Kathryn G. McIntosh, Robert P. Currier, Anthony E. Williams‐Jones, Xiaofeng Guo

Bibliographic record

VenueNature Geoscience · 2022
Typearticle
Languageen
FieldEarth and Planetary Sciences
TopicGeochemistry and Elemental Analysis
Canadian institutionsMcGill University
Fundersnot available
KeywordsRare-earth elementLutetiumHydrothermal circulationRare earthFluoriteMineralGeologyGeochemistryEarth (classical element)MineralogyMaterials scienceYttriumMetallurgy

Abstract

fetched live from OpenAlex

Emerging renewable energy technologies and low-carbon transportation rely heavily on the unique optical and magnetic properties of the rare earth elements. The medium to heavy rare earth elements, neodymium to lutetium, are most sought by industry but are the least abundant in nature. Only a small proportion of known rare earth element deposits are enriched in these elements. Identifying additional sources of medium to heavy rare earth elements for resource exploration requires improved understanding of the mechanisms responsible for the formation of such highly fractionated deposits. Here we report the results of experiments demonstrating a mechanism that could lead to enrichment of medium to heavy rare earth elements in ore-forming hydrothermal systems. In our experiments, we simulated natural hydrothermal systems by heating a column containing apatite and fluorite through which we pumped a chloride-rich solution bearing rare earth elements. Analysis of our experiments shows that the fluoride mineral fluocerite can serve as a precursor phase that fractionates rare earth elements before it is subsequently converted to a thermodynamically more stable mineral. Our findings identify geological settings in which fluocerite is observed or predicted to occur as potential exploration targets for deposits enriched in medium to heavy rare earth elements. Experiments under simulated hydrothermal conditions suggest that the mineral fluocerite may serve as an intermediate phase that fractionates the rare earth elements in ore-forming systems.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesInsufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Observational · Consensus signal: Observational
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.293
Threshold uncertainty score0.998

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.001
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0030.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.005
GPT teacher head0.219
Teacher spread0.214 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designObservational
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations35
Published2022
Admission routes1
Has abstractyes

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