Front Cover: Heterobimetallic Ln(III)‐Containing Materials Based on One‐Dimensional Aurophilic Chains of Gold(I) Dithiolate Dimers and Their Vapochromic Response to DMF (Eur. J. Inorg. Chem. 14/2022)
Bibliographic record
Abstract
The Front Cover shows the luminescence turn-on response of a gold(I)-containing dithiolate complex after exposure to dimethylformamide (DMF) vapor. The switch represents the toggleable nature of this response, as the complex is non-luminescent in the absence of DMF. The intensity of the luminescence depends on the concentration of DMF present. The structure of the luminescent gold(I) dithiolate is depicted, with chains affixed to the gold(I) atoms, symbolic of the aurophilic interactions binding each monomeric unit into polymeric one-dimensional chains. Notably, in these materials, the observed emission energy may be dependent on more than just the length of the aurophilic interactions. More information can be found in the Research Article by D. B. Leznoff and co-workers.
Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.
How this classification was reachedexpand
Full frame machine prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.
Distilled classifier scores by category (both heads)
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.001 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.063 | 0.014 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".