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Record W4230054535 · doi:10.1002/0470862106.ia477

Medicinal Inorganic Chemistry: Using Toxicity to Advantage

2005· other· en· W4230054535 on OpenAlexaff
Katherine H. Thompson

Bibliographic record

VenueEncyclopedia of Inorganic Chemistry · 2005
Typeother
Languageen
FieldMedicine
TopicMetal complexes synthesis and properties
Canadian institutionsUniversity of British Columbia
Fundersnot available
KeywordsCisplatinCarboplatinOxaliplatinArsenic trioxideCancer researchChemistryCancerPharmacologyMedicineArsenicChemotherapyInternal medicine

Abstract

fetched live from OpenAlex

Abstract The field of metal‐based compounds intended for treatment of cancer has long been dominated by cisplatin, first approved for clinical use in treating testicular cancer, in 1978. By all accounts, cisplatin has been a resounding success. Other platinum‐based compounds have been introduced since then, with carboplatin and oxaliplatin serving to broaden the range of tumors that can be effectively treated. Overcoming tumor cell resistance is an ongoing problem, and the target of many newer platinum‐based anticancer therapeutic agents. More recently, substitution of platinum with other metal ions, such as ruthenium, gallium, lanthanides, and arsenic, has expanded the array of potential metal‐based anticancer agents, with the arsenic trioxide having particular success against acute promyelocytic leukemia (APL). A key feature of metal‐based anticancer therapeutic agents is that they are toxic by design: without toxicity, the tumor cells could not be eliminated. Similar strategies are useful for diseases such as malaria, Chagas disease, and leishmaniasis, in which the target organisms are parasites. For parasitic diseases, as well as for resistant bacterial infections, or to stop tumor growth, the requirement for appropriate metallotherapeutic design is to minimize contact with healthy tissue, to target particular cells, and to avoid premature release of the metal ion.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.001
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow), Insufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: none
GenreCandidate signal: Other · Consensus signal: Other
Teacher disagreement score0.433
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.001
Meta-epidemiology (narrow)0.0010.001
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0010.000
Research integrity0.0010.001
Insufficient payload (model declined to judge)0.0760.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.016
GPT teacher head0.262
Teacher spread0.246 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designBench or experimental
Domainnot available
GenreOther

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2005
Admission routes1
Has abstractyes

Explore more

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