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A novel integrated rotary reactor for NOx reduction by CO and air preheating: NOx removal performance and mechanism

2021· preprint· en· W4231544281 on OpenAlexaff
Peiliang Sun, Jianjie Li, Xingxing Cheng, Xiangdong Li, Xiaotao Bi, Zhiqiang Wang

Bibliographic record

Venuenot available
Typepreprint
Languageen
FieldMaterials Science
TopicCatalytic Processes in Materials Science
Canadian institutionsUniversity of British Columbia
Fundersnot available
KeywordsNOxCatalysisAdsorptionChemistryWaste managementChemical engineeringChemical reactorMaterials scienceEnvironmental scienceNuclear engineeringProcess engineeringEngineeringCombustionPhysical chemistry

Abstract

fetched live from OpenAlex

A novel integrated rotary reactor for NOx reduction by CO and air preheating (iNA reactor) was proposed. NOx removal performance was investigated in a fixed-bed reactor, which was used to simulate the working conditions change in iNA reactor. Lab-synthesized Cu/FeCeOx were used as catalyst. Two different modes were tested with iNA reactor: short cycles and long cycles. Excellent NOx removal efficiencies of over 95% and 90% for short cycles and long cycles were observed in iNA reactor. Moreover, compared with the constant-temperature rotary reactor, better H2O and SO2 resistances were also found in iNA reactor. The reaction mechanism was proposed based on in-situ DRIFT study. NOx was stored as nitrates in the adsorption zone, and then decomposed rapidly by both high temperatures and CO, leading to the deep catalyst regeneration. Therefore, temperature swinging and the feed of CO were key to having high iNA reactor performance for NOx removal.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.001
Threshold uncertainty score0.003

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0010.000
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.001
Open science0.0010.000
Research integrity0.0010.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.019
GPT teacher head0.262
Teacher spread0.243 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2021
Admission routes1
Has abstractyes

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