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Record W4231598131 · doi:10.1002/ange.201709932

Brass and Bronze as Effective CO<sub>2</sub> Reduction Electrocatalysts

2017· article· en· W4231598131 on OpenAlexafffund
Jingfu He, Kevan E. Dettelbach, Aoxue Huang, Curtis P. Berlinguette

Bibliographic record

VenueAngewandte Chemie · 2017
Typearticle
Languageen
FieldEnergy
TopicCO2 Reduction Techniques and Catalysts
Canadian institutionsUniversity of British Columbia
FundersNatural Sciences and Engineering Research Council of CanadaCanadian Institute for Advanced Research
KeywordsOverpotentialFormateTernary operationBrassFaraday efficiencyMaterials scienceCatalysisInorganic chemistryBronzeCopperMetallurgyChemical engineeringChemistryElectrochemistryElectrodePhysical chemistryOrganic chemistry

Abstract

fetched live from OpenAlex

Abstract Electrochemically reducing CO 2 into fuels using renewable electricity is a contemporary global challenge that requires significant advances in catalyst design. Photodeposition techniques were used to screen ternary alloys of Cu‐Zn‐Sn, which includes brass and bronze, for the electrocatalytic reduction of CO 2 to CO and formate. This analysis identified Cu 0.2 Zn 0.4 Sn 0.4 and Cu 0.2 Sn 0.8 to be capable of reaching Faradaic efficiencies of &gt;80 % for CO and formate formation, respectively, and capable of achieving partial current densities of 3 mA cm −2 at an overpotential of merely 200 mV.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.039
Threshold uncertainty score0.960

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.009
GPT teacher head0.259
Teacher spread0.250 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations20
Published2017
Admission routes2
Has abstractyes

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