The Preparation and X‐ray Crystal Structure of [(AgI<sub>2</sub>)<sub><i>n</i></sub>]⋅<i>n</i> MF<sub>6</sub> (M=Sb, As): Diiodine Acting as a Donor in the Planar Polymeric [(AgI<sub>2</sub>)<sub><i>n</i></sub>]<sup><i>n</i>+</sup>
Bibliographic record
Abstract
Großzügiges Iod: Die Reaktionen von AgMF6 mit I2 in flüssigem SO2 liefern [(AgI2)n]⋅n MF6 (M=Sb, As). Diese Festkörper bestehen aus [(AgI2)n]n+-Ketten, die entlang der c-Achse gestapelt und durch Schichten von [MF6]−-Ionen voneinander getrennt sind (siehe Bild). [(AgI2)n]n+ ist die erste homoleptische Molekül-Dihalogen-Spezies und eines von wenigen Beispielen, in denen molekulares I2 als Donor koordiniert ist.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.002 | 0.001 |
| Meta-epidemiology (narrow) | 0.003 | 0.003 |
| Meta-epidemiology (broad) | 0.003 | 0.001 |
| Bibliometrics | 0.000 | 0.002 |
| Science and technology studies | 0.002 | 0.001 |
| Scholarly communication | 0.001 | 0.002 |
| Open science | 0.003 | 0.001 |
| Research integrity | 0.002 | 0.003 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; both teacher heads agree on what is shown here.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".