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Record W4233009582 · doi:10.1002/0470027320.s6105

Vibrational Spectroscopy of Polymer Composites

2001· other· en· W4233009582 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.

Bibliographic record

VenueHandbook of Vibrational Spectroscopy · 2001
Typeother
Languageen
FieldArts and Humanities
TopicCultural Heritage Materials Analysis
Canadian institutionsNational Research Council Canada
Fundersnot available
KeywordsThermosetting polymerMaterials scienceComposite materialPolymerRaman spectroscopyCuring (chemistry)ThermoplasticCrystallinityNanocompositeComposite numberInfrared spectroscopyCarbon nanotubeCelluloseChemical engineeringChemistryOrganic chemistry

Abstract

fetched live from OpenAlex

Abstract The chapter reviews and illustrates with examples the diverse applications of vibrational spectroscopy to the study of polymer composites, which are defined as materials consisting of a polymeric (thermoplastic or thermoset) matrix reinforced with fibers (carbon, glass, polymer) or inorganic particles. After some discussion of the experimental difficulties that must be dealt with in obtaining spectra of these heterogeneous materials, the literature is reviewed under the following subject categories: quality control of polymer composites; studies of reinforcements (carbon, glass, polymer fibers, inorganic particulate fillers, cellulose‐based fillers), their surface treatments, and interphases; thermoplastic matrices (crystallinity, orientation); thermoset matrices (the study and monitoring of curing by mid‐infrared, near‐infrared, and Raman spectroscopies); environmental degradation. The chapter concludes with a brief coverage of newer types of composite materials: nanocomposites based on layered silicates (nanoclays), sol–gel preparation methods, and carbon nanotubes; molecular composites; and polymer‐dispersed liquid crystals.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow), Insufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Other · Consensus signal: Other
Teacher disagreement score0.393
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0000.000
Science and technology studies0.0000.001
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.2150.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.017
GPT teacher head0.237
Teacher spread0.221 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it