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Record W4233329850 · doi:10.26434/chemrxiv.13322771

Ten Essential Delocalization Learning Outcomes: How Well Are They Achieved?

2020· preprint· en· W4233329850 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.
fundA Canadian funder is recorded on the work.

Bibliographic record

VenueChemRxiv · 2020
Typepreprint
Languageen
FieldChemistry
TopicVarious Chemistry Research Topics
Canadian institutionsUniversity of Ottawa
FundersSocial Sciences and Humanities Research Council of Canada
KeywordsDelocalized electronMathematics educationPsychologyResonance (particle physics)EpistemologyClass (philosophy)ChemistryCognitive psychologyArtificial intelligenceComputer sciencePhysicsPhilosophyOrganic chemistryAtomic physics

Abstract

fetched live from OpenAlex

<p>Delocalization (resonance) is a concept in organic chemistry that influences the chemical reactivity, structure, and physical properties of molecules. However, the concept has proven challenging for students and the related learning outcomes had previously been only vaguely defined. We recently defined ten essential learning outcomes about delocalization that a student should be able to demonstrate by the end of a two-course organic chemistry sequence. The goal of the present study was to investigate to what extent the ten LOs were achieved by students, as well as the connections between the LOs. We analyzed three exam questions related to seven of the ten LOs for the degree of achievement, common errors, and scientific reasoning. We found that students sometimes struggled to identify when delocalization could occur, that some of the LOs built on one another, and that students were more successful in drawing resonance structures when explicitly asked, but less successful when the requirement was implicit or embedded within a mechanism. Our analysis of student reasoning showed that the dominant modes of reasoning were aligned with the related expectations and explanations in the course. When asked to justify the contribution of resonance structures to the resonance hybrid, most answers used a descriptive mode of reasoning; when asked to explain why a given proton was more acidic than another, most answers contained relational and linear causal reasoning. Implications for research and practice are discussed.</p>

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.001
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow), Research integrity, Insufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.428
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.001
Meta-epidemiology (narrow)0.0010.001
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0010.002
Research integrity0.0010.003
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.029
GPT teacher head0.282
Teacher spread0.252 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it