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Record W4233433465 · doi:10.1002/ange.201004445

Block Copolymers Comprising π‐Conjugated and Liquid Crystalline Subunits: Induction of Macroscopic Nanodomain Orientation

2010· article· en· W4233433465 on OpenAlexaff
Dehui Han, Xia Tong, Yi Zhao, Yue Zhao

Bibliographic record

VenueAngewandte Chemie · 2010
Typearticle
Languageen
FieldMaterials Science
TopicBlock Copolymer Self-Assembly
Canadian institutionsUniversité de Sherbrooke
Fundersnot available
KeywordsCopolymerConjugated systemBlock (permutation group theory)Polymer scienceChemistryMaterials scienceStereochemistryComputer scienceCombinatoricsMathematicsPolymerOrganic chemistry

Abstract

fetched live from OpenAlex

Einmal um den Block: Ein Blockcopolymer enthält regioreguläres Poly(3-hexylthiophen) (P3HT) und ein Azobenzol-haltiges Flüssigkristallpolymer (SCLCP) in der Seitenkette. Weil die Klärtemperatur des SCLCP-Blocks über der Schmelztemperatur von P3HT liegt, können die Oberflächen- und lichtinduzierte Ausrichtung von Mesogenen im SCLCP-Block zur Anordnung streifenförmiger P3HT-Nanodomänen genutzt werden (siehe Phasenkontrast-AFM-Bild). Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.001
Threshold uncertainty score0.798

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.010
GPT teacher head0.246
Teacher spread0.235 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations5
Published2010
Admission routes1
Has abstractyes

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