MétaCan
Menu
Back to cohort
Record W4235999828 · doi:10.1002/047084289x.rb271

Bromoacetyl Chloride

2001· reference-entry· en· W4235999828 on OpenAlexaff
J. Michael Chong

Bibliographic record

VenueEncyclopedia of Reagents for Organic Synthesis · 2001
Typereference-entry
Languageen
FieldChemistry
TopicChemical Synthesis and Reactions
Canadian institutionsUniversity of Waterloo
Fundersnot available
KeywordsBifunctionalReagentChlorideKeteneChemistryHydrolysisBlock (permutation group theory)Nuclear chemistryOrganic chemistryMathematicsCatalysis

Abstract

fetched live from OpenAlex

[22118-09-8] C2H2BrClO (MW 157.39) InChI = 1S/C2H2BrClO/c3-1-2(4)5/h1H2 InChIKey = SYZRZLUNWVNNNV-UHFFFAOYSA-N (bifunctional building block;1-8 ketene precursor;9-12 bromoacetylating agent13, 14) Physical Data: bp 127–128 °C; d 1.908 g cm−3. Form Supplied in: colorless liquid, 98% pure or in lower grades [contaminated with BrCH2C(O)Br and ClCH2C(O)Cl]; widely available. Handling, Storage, and Precautions: readily hydrolyzed with formation of HCl; corrosive; lachrymator. This reagent should only be handled in a fume hood.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.001
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Not applicable · Consensus signal: none
GenreCandidate signal: Other · Consensus signal: Other
Teacher disagreement score0.078
Threshold uncertainty score0.260

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0010.001
Meta-epidemiology (narrow)0.0020.001
Meta-epidemiology (broad)0.0010.001
Bibliometrics0.0010.001
Science and technology studies0.0010.000
Scholarly communication0.0010.001
Open science0.0030.001
Research integrity0.0010.002
Insufficient payload (model declined to judge)0.0780.071

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.017
GPT teacher head0.244
Teacher spread0.227 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designNot applicable
Domainnot available
GenreOther

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2001
Admission routes1
Has abstractyes

Explore more

Same venueEncyclopedia of Reagents for Organic SynthesisSame topicChemical Synthesis and ReactionsFrench-language works237,207