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Record W4236210987 · doi:10.26434/chemrxiv-2021-sjv53

Are substitutes to Cd-based quantum dots in displays more sustainable, effective, and cost competitive? An alternatives assessment approach

2021· preprint· en· W4236210987 on OpenAlexafffund
Aude Béchu, Subhasis Ghoshal, Audrey Moores, Niladri Basu

Bibliographic record

VenueChemRxiv · 2021
Typepreprint
Languageen
FieldEngineering
TopicGreen IT and Sustainability
Canadian institutionsMcGill University
FundersFonds Québécois de la Recherche sur la Nature et les TechnologiesNatural Sciences and Engineering Research Council of CanadaCanada Research ChairsMcGill University
KeywordsOLEDNanomaterialsNanotechnologyComputer scienceHazardQuantum dotSustainabilityMaterials scienceRisk analysis (engineering)ChemistryBusiness

Abstract

fetched live from OpenAlex

Light emissive organics and inorganic nanoparticles are substance classes competing for applications in displays in the form of organic LEDs (OLEDs) and quantum LEDs (QLEDs), respectively. Upcoming substance classes (perovskites) and Q-OLED displays also contain novel nanomaterials and organics for these applications. However, the sustainability of these emissive substances is difficult to assess quickly and broadly because of their complexity, their inherently different structures, and their rapid evolution in the literature. We propose the use of an alternatives assessment to compare the hazard, cost, and performance of these competing substances, with a focus on replacing cadmium-containing quantum dots. The cost assessment highlights competitiveness of OLEDs because of their low amounts needed per display, but performance assessments do not identify a preferred alternative. The hazard results indicate there is no clear alternative either, with each novel nanomaterial or organic substance having different negative aspects. These results identify the need for a low-hazard high-performing alternative substance, and the assessment provides a framework for researchers to evaluate their own novel substances.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Observational · Consensus signal: Observational
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.211
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0010.001
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.001
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.013
GPT teacher head0.275
Teacher spread0.262 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designObservational
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2021
Admission routes2
Has abstractyes

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