Solving the Colouring Problem in Half-Heusler Structures: Machine-Learning Predictions and Experimental Validation
Bibliographic record
Abstract
The site preferences within the structures of half-Heusler compounds have been evaluated through a machine-learning approach. A support-vector machine algorithm was applied to develop a model which was trained on 179 experimentally reported structures and 23 descriptors based solely on the chemical composition. The model gave excellent performance, with sensitivity of 93%, selectivity of 96%, and accuracy of 95%. As an illustration of data sanitization, two compounds (GdPtSb, HoPdBi) flagged by the model to have potentially incorrect site assignments were resynthesized and structurally characterized. The predictions of the correct site assignments from the machine-learning model were confirmed by single-crystal and powder X-ray diffraction analysis. These site assignments also corresponded to the lowest total energy configurations as revealed from first-principles calculations.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.001 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.001 |
| Research integrity | 0.000 | 0.001 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".