Frontispiece: Low‐Symmetry Ω‐Shaped Zinc Phthalocyanine Sensitizers with Panchromatic Light‐Harvesting Properties for Dye‐Sensitized Solar Cells
Bibliographic record
Abstract
Panchromatic Phthalocyanine Sensitizer A π-conjugation side chain with an adsorption site was introduced at an α position of a zinc phthalocyanine (ZnPc) macrocycle. The compound (αPcS1) shows a red shifted Q band and a broad absorption band from 350 to 550 nm, which is assigned to the intramolecular charge-transfer transition from the ZnPc core to the side chains. TD-DFT calculations provide a clear interpretation of the effect of the thiophene conjugation on the typical π molecular orbitals of the Pc core. The αPcS1 cell showed a panchromatic response in the range 400–800 nm with a power conversion efficiency of 5.5 % when used as a light-harvesting dye on a TiO2 electrode for the dye-sensitized solar cell under one-sun conditions. For more information, see the Full Paper by M. Kimura et al. on page 18760 ff.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.001 | 0.000 |
| Meta-epidemiology (narrow) | 0.001 | 0.001 |
| Meta-epidemiology (broad) | 0.002 | 0.001 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.001 | 0.000 |
| Scholarly communication | 0.001 | 0.000 |
| Open science | 0.001 | 0.000 |
| Research integrity | 0.000 | 0.002 |
| Insufficient payload (model declined to judge) | 0.003 | 0.004 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; both teacher heads agree on what is shown here.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".