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Calcium Chloride

2000· other· en· W4237530995 on OpenAlexaboutno aff
Kenneth I. G. Reid, Roger Kust

Bibliographic record

VenueKirk-Othmer Encyclopedia of Chemical Technology · 2000
Typeother
Languageen
FieldMaterials Science
TopicCalcium Carbonate Crystallization and Inhibition
Canadian institutionsnot available
Fundersnot available
KeywordsCalciumDissolutionSolubilityChlorideAqueous solutionChemistryMineralogyOrganic chemistry

Abstract

fetched live from OpenAlex

Abstract Calcium chloride, CaCl 2 , is a white, crystalline salt that is very soluble in water. Solutions containing 30–45 wt % CaCl 2 are used commercially. Of the alkaline‐earth chlorides it is the most soluble in water. It is extremely hygroscopic and liberates large amounts of heat during water absorption and on dissolution. It forms a series of hydrates containing one, two, four, and six moles of water per mole of calcium chloride. Commercial applications of calcium chloride and its hydrates exploit one or more of its properties with regard to aqueous solubility, hygroscopic nature, the heat gained or lost when one hydrated phase changes to another. Because of high solubility in water, calcium chloride is used to obtain solutions having relatively high densities. Viscosity is an important property of calcium chloride solutions in terms of engineering design and in application of such solutions to flow‐through porous media. Significant quantities of calcium chloride are produced in the United States, Canada, Mexico, Germany, Belgium, Sweden, Finland, Norway, and Japan. In the United States the principal route for making calcium chloride is by the evaporation of underground brines. The primary CaCl 2 markets have not changed since the 1950s. Significant markets in the United States are for deicing during the winter and roadbed stabilization, and as a dust palliative during the summer. Use as an accelerator in the ready‐mix concrete industry is sizable but there is concern about the possible corrosion of steel in highways and buildings. Calcium chloride is also used in oil and gas well drilling. Food‐grade calcium chloride is used in cheese making to aid in rennet coagulation and to replace calcium lost in pasteurization. In the canning industry it is used to firm the skin of fruit such as tomatoes, cucumbers, and jalapenos. Food‐grade calcium chloride is used in the brewing industry as a basic component of certain beers. Above certain levels chloride is toxic to plants and animals. Calcium chloride solutions are used as antispasmodics, diuretics and in the treatment of tetany. Concentrated solutions of calcium chloride cause erythema, exfoliation, ulceration, and scarring of the skin. Injections into the tissue may cause necrosis. If given orally calcium chloride can cause irritation to the gastrointestinal tract unless accompanied by a demulcent. Calcium chloride has been give a toxicity or hazard level of 3.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow), Research integrity, Insufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: none
GenreCandidate signal: Other · Consensus signal: Other
Teacher disagreement score0.252
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0010.001
Science and technology studies0.0000.001
Scholarly communication0.0000.000
Open science0.0010.000
Research integrity0.0010.000
Insufficient payload (model declined to judge)0.0170.001

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.008
GPT teacher head0.239
Teacher spread0.231 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designBench or experimental
Domainnot available
GenreOther

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2000
Admission routes1
Has abstractyes

Explore more

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