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Cayleyan Sn-encoded SU(2)×Sn↓G embeddings: Nuclear spin permutation symmetries via polyhedral lattice-point models, for modulo-i χ(Ci(Sn↓G)) combinatorial invariance sets

2000· article· en· W4238577429 on OpenAlexaff
F.P. Temme

Bibliographic record

VenueInternational Journal of Quantum Chemistry · 2000
Typearticle
Languageen
FieldPhysics and Astronomy
TopicAdvanced Chemical Physics Studies
Canadian institutionsQueen's University
Fundersnot available
KeywordsModuloHomogeneous spacePermutation (music)Lattice (music)CombinatoricsSpin (aerodynamics)Point (geometry)PhysicsMathematicsGeometryThermodynamics

Abstract

fetched live from OpenAlex

The complete nuclear permutational (CNP) statistics of SU(2)×𝒮n spin ensembles of forms [A]n/[AX]n for cage molecules [i.e., exclusive (not mixed-isotope) isotopomers] are shown to yleld totally analytic invariance sets on the basis of vertex-point spins (or more generally Schur function labels) on regular polyhedral lattice-point models and their modulo-i [of Ci (𝒮n↓𝒢)] algebras in the specific cases discussed. This occurs only when (i.e., iff) they correspond to the criterion for Cayleyan group embedding or index n=/𝒢/. Such realizations correspond to 𝒮n symbolic (lattice-based) encodings, well known in cybernetics. Hence exclusively combinatorial invariance descriptions [within (Voronoi) vertex-point lattice geometric models], within j≡0 mod(i) (equivalence modulo-i) for each of i indices of the class operators (of the embedded group) Cis, else a null factor, arise for certain specific automorphic CNP/NMR spin symmetries; to date these are shown to be limited to some five main Cayleyan types of SU(2)×𝒮n↓𝒢 embedding. Both the question of the sufficiency of Cayley criterion for dual group embeddings beyond SU(m≥3)×𝒮n and that of the further role of Kostka coefficient hierarchy in the natural embedding process, are reviewed here and more extensively in related work [Eur. Phys. J., B 11, 177 (1999); Int. J. Quant. Chem., 78(1), 5–14 (2000)]. A brief comment on the value of Yamanouchi chain-based system invariants reaffirms the central role of the 𝒮n group and its encodings in subduction processes associated with spin algebras and in certain fundamental Liouvillian (bosonic) mapping processes [Physica, A198, 245 (1993)]. In highlighting these linkages between subtopics, we demonstrate the ultimate consequences of Balasubramanian's use of automorphisms, based on the {Jij} zeroth-order structure, in NMR [J. Chem. Phys., 78, 6258 (1983)], or equally his use of cycle-index methods in CNP statistics. © 2000 John Wiley & Sons, Inc. Int J Quant Chem 78: 71–82, 2000

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.001
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Theoretical or conceptual · Consensus signal: Theoretical or conceptual
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.005
Threshold uncertainty score0.016

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.001
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0010.000
Science and technology studies0.0010.002
Scholarly communication0.0020.001
Open science0.0010.001
Research integrity0.0010.001
Insufficient payload (model declined to judge)0.0050.001

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.012
GPT teacher head0.280
Teacher spread0.268 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designTheoretical or conceptual
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

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Citations0
Published2000
Admission routes1
Has abstractyes

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