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Record W4238913682 · doi:10.22215/etd/2021-14563

Inference of Hydroxyl Radical Abundances from Combined Satellite and Ground-Based Hydrochlorofluorocarbon Observations

2021· dissertation· en· W4238913682 on OpenAlexaffabout
Rufes John Sundarraj

Bibliographic record

Venuenot available
Typedissertation
Languageen
FieldEarth and Planetary Sciences
TopicAtmospheric Ozone and Climate
Canadian institutionsCarleton University
Fundersnot available
KeywordsHydroxyl radicalAtmosphere (unit)SatelliteEnvironmental scienceLatitudeLinear regressionMeteorologyAtmospheric sciencesTropopauseTropicsClimatologyChemistryGeographyStratosphereMathematicsStatisticsGeodesyPhysicsGeologyRadicalBiologyEcologyOrganic chemistry

Abstract

fetched live from OpenAlex

Until recently, Methyl Chloroform was used as a bellwether to determine OH levels but due to its declining concentrations, the need for other means to calculate OH levels is imminent.This work proposes a new way of using three different tracers (HFC134a, HCFC141b, and HCFC142b) to determine hydroxyl levels in the atmosphere using a 9box model.The annual trends of each gas were obtained and it was found that there has not been a significant drop but an increase in two of the tracers' levels despite the implementation of Montreal Protocol.The tropopause was defined around 13kms in the northern and southern latitudes and around 17kms in the tropics.With the regions of each box defined, and the concentrations of the tracers obtained from ACE-FTS instrument and NOAA, the OH levels in the atmosphere were obtained through least-squares estimation.The surface regions showed the closest estimates at 5.35 x 10 5 molecules/cm 3 over the tropics and around 1.1 x 10 5 molecules/cm 3 over the other two bands.The global averages across troposphere and stratosphere were about 10 and 12 times lower than the traditionally observed values of about 10 x 10 5 molecules/cm 3 and 1 x 10 5 molecules/cm 3 .However, future works could potentially lead to the model observing closer estimates.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.001
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Observational · Consensus signal: Observational
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.008
Threshold uncertainty score0.015

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.001
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0010.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.018
GPT teacher head0.232
Teacher spread0.214 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designObservational
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2021
Admission routes2
Has abstractyes

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