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Record W4239407847 · doi:10.1002/047084289x.rn01275

Zinc Fluoride

2011· reference-entry· en· W4239407847 on OpenAlexaff
Marc‐Olivier Turcotte‐Savard, Jean‐François Paquin

Bibliographic record

VenueEncyclopedia of Reagents for Organic Synthesis · 2011
Typereference-entry
Languageen
FieldChemistry
TopicInorganic Fluorides and Related Compounds
Canadian institutionsUniversité Laval
Fundersnot available
KeywordsZincFluorideChemistrySolubilityNuclear chemistryBottleInorganic chemistryMaterials scienceOrganic chemistry

Abstract

fetched live from OpenAlex

[7783-49-5] ZnF2 (MW 103.39) InChI = 1S/2FH.Zn/h2*1H;/q;;+2/p-2 InChIKey = BHHYHSUAOQUXJK-UHFFFAOYSA-L (Lewis acid, fluorination agent) Physical Data: mp 872 °C; bp 1500 °C; d 4.95 g cm−3 at 25 °C. Solubility: sparingly sol in H2O (1.51 g 100 mL−1), but more sol in HCl, HNO3, and NH4OH. Also slightly sol in HF. Form Supplied in: white solid; widely available. Purification: the most frequent impurity is H2O and it can be removed by heating at 100 °C in a dry atmosphere. Handling, Storage, and Precautions: zinc fluoride is a moderate irritant of the respiratory tract, as well as for the skin and eye. Zinc fluoride should be manipulated in a well-ventilated fume hood, while avoiding dust formation. Dust mask or respirators may prevent dust inhalation. Skin and eye contact may be avoided by the appropriate use of gloves and safety goggles. Zinc fluoride must be stored in a tightly closed container and kept in a dry and well-ventilated place.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesInsufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Not applicable · Consensus signal: none
GenreCandidate signal: Other · Consensus signal: Other
Teacher disagreement score0.906
Threshold uncertainty score0.314

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0010.001
Meta-epidemiology (broad)0.0010.001
Bibliometrics0.0010.001
Science and technology studies0.0010.000
Scholarly communication0.0010.001
Open science0.0020.001
Research integrity0.0010.001
Insufficient payload (model declined to judge)0.0940.058

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.016
GPT teacher head0.225
Teacher spread0.209 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

Study designNot applicable
Domainnot available
GenreOther

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations2
Published2011
Admission routes1
Has abstractyes

Explore more

Same venueEncyclopedia of Reagents for Organic SynthesisSame topicInorganic Fluorides and Related CompoundsFrench-language works237,207