Investigation of the effect of two new initiators of p-aminoazobenzene and diazoaminobenzene on the properties of polyaniline
Bibliographic record
Abstract
The flower-like dendrimer and the nanosheet synthesis of polyaniline in the template-free method (rapid mixing) have been done successfully using p-aminoazobenzene (PAAB) and diazoaminobenzene (DAAB) as two new initiators, respectively.In both syntheses, the ammonium peroxydisulfate is used as an oxidant.The effect of initiators on the morphology is demonstrated by scanning electron microscopy (SEM) and transmission electron microscopy (TEM) images, and the mechanism of nanostructure formation is presented.The polymers are characterized by Fourier transform infrared (FT-IR) and Ultraviolet-visible (UV-vis) spectroscopies and elemental analysis (CHNS).Cyclic voltammetry (CV), electrical conductivity, X-ray diffraction (XRD) and thermogravimetric analysis (TGA) are also presented.Both polymers are semi-crystalline in nature and had the same thermal behavior.
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How this classification was reachedexpand
Full frame machine prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.
Distilled classifier scores by category (both heads)
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.001 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".