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Record W4240829801 · doi:10.1002/047084289x.ra035

Acrylic Acid

2001· reference-entry· en· W4240829801 on OpenAlexaff
Patrick H. M. Delanghe, Mark Lautens

Bibliographic record

VenueEncyclopedia of Reagents for Organic Synthesis · 2001
Typereference-entry
Languageen
FieldChemistry
TopicVarious Chemistry Research Topics
Canadian institutionsUniversity of Toronto
Fundersnot available
KeywordsChemistryPolymerizationAcrylic acidAcetoneAnhydrousBenzeneOrganic chemistryEtherSolubilityIsopropyl alcoholMonomerPolymer

Abstract

fetched live from OpenAlex

[79-10-7] C3H4O2 (MW 72.06) (acylating agent, electrophile in 1,4-addition reactions, dienophile in Diels–Alder reactions) Alternate Name: propenoic Acid. Physical Data: mp −13 °C; bp 139 °C; d 1.051 g cm−3; nD 1.4224. Solubility: miscible with water, alcohol, ether, acetone, and benzene. Form Supplied in: colorless liquid (stabilized with 200 ppm hydroquinone monomethyl ether); widely available. Purification: can be purified by steam distillation, or vacuum distillation through a column packed with copper gauze to inhibit polymerization (this treatment also removes inhibitors such as methylene blue that may be present). Azeotropic removal of the water with benzene converts wet acrylic acid into the anhydrous material. Handling, Storage, and Precautions: polymerization occurs readily in the presence of oxygen. The liquid is toxic, corrosive, has an acrid odor, and fumes. Use in a fume hood.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.004
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow), Research integrity, Insufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Not applicable · Consensus signal: Not applicable
GenreCandidate signal: Other · Consensus signal: Other
Teacher disagreement score0.386
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.004
Meta-epidemiology (narrow)0.0010.001
Meta-epidemiology (broad)0.0010.001
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0020.000
Research integrity0.0020.001
Insufficient payload (model declined to judge)0.0370.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.024
GPT teacher head0.273
Teacher spread0.249 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designNot applicable
Domainnot available
GenreOther

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2001
Admission routes1
Has abstractyes

Explore more

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