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Record W4240840421 · doi:10.1002/047084289x.rb284

<i>B</i>-Bromocatecholborane

2001· reference-entry· en· W4240840421 on OpenAlexaff
Paul C. Anderson, Yvan Guindon

Bibliographic record

VenueEncyclopedia of Reagents for Organic Synthesis · 2001
Typereference-entry
Languageen
FieldChemistry
TopicChemical Reactions and Mechanisms
Canadian institutionsBoehringer Ingelheim (Canada)
Fundersnot available
KeywordsDichloromethaneChemistryMoistureReagentSolid acidOrganic chemistryCatalysisSolvent

Abstract

fetched live from OpenAlex

[51901-85-0] C6H4BBrO2 (MW 198.81) InChI = 1S/C6H4BBrO2/c8-7-9-5-3-1-2-4-6(5)10-7/h1-4H InChIKey = SAILTPCYIYNOEL-UHFFFAOYSA-N (mild Lewis acid capable of selective cleavage of ether, ester and carbamate protecting groups;1, 2 catalyst for Diels–Alder reactions3, 4) Alternate Name: 2-bromo-1,3,2-benzodioxaborole. Physical Data: mp 47 °C; bp 76 °C/9 mmHg; fp 41 °C. Solubility: sol dichloromethane. Form Supplied in: colorless solid which fumes in air. Preparative Method: can be conveniently prepared by treating Catechol with Boron Tribromide.1, 2, 5 The reagent is isolated by distillation as a moisture-sensitive, low-melting solid. Handling, Storage, and Precautions: flammable solid, moisture sensitive; may be conveniently stored and dispensed as a 0.2 M solution in dichloromethane. If properly protected from moisture, these solutions are stable for a period of months.1 Use in a fume hood.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.002
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow), Insufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Not applicable · Consensus signal: none
GenreCandidate signal: Other · Consensus signal: Other
Teacher disagreement score0.505
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.002
Meta-epidemiology (narrow)0.0010.001
Meta-epidemiology (broad)0.0010.001
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0010.000
Research integrity0.0010.001
Insufficient payload (model declined to judge)0.0290.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.016
GPT teacher head0.248
Teacher spread0.231 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designNot applicable
Domainnot available
GenreOther

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2001
Admission routes1
Has abstractyes

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