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Record W4243935308 · doi:10.1002/9780470975800.ch8

Nucleophilic Aliphatic Substitution

2007· other· en· W4243935308 on OpenAlexaff
Kenneth Charles Westaway

Bibliographic record

VenueOrganic Reaction Mechanisms/Organic reaction mechanisms · 2007
Typeother
Languageen
FieldChemistry
TopicChemical Reaction Mechanisms
Canadian institutionsLaurentian University
Fundersnot available
KeywordsSubstitution (logic)Nucleophilic substitutionChemistryOrganic chemistryComputer scienceProgramming language

Abstract

fetched live from OpenAlex

This chapter contains sections titled: S N Reactions Forming CC Bonds Allylic and Vinylic Substitutions Reactions of Cyclic Ethers Aziridines and Other Small Ring Substitutions Studies Using Kinetic Isotope Effects Nucleophilic Substitution on Elements Other than Carbon Medium Effects/Solvent Effects Micelles and Ion-pair Aggregates in Substitution Reactions Structural Effects Theoretical Studies Gas-phase Substitution Reactions Miscellaneous Kinetic and Product Studies S N Reactions Producing Polymers Acknowledgement References

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.002
metaresearch head score (Gemma)0.001
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow), Research integrity, Insufficient payload (model declined to judge)
Consensus categoriesMeta-epidemiology (narrow), Research integrity, Insufficient payload (model declined to judge)
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Other · Consensus signal: Other
Teacher disagreement score0.363
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0020.001
Meta-epidemiology (narrow)0.0030.003
Meta-epidemiology (broad)0.0020.001
Bibliometrics0.0030.003
Science and technology studies0.0010.000
Scholarly communication0.0000.001
Open science0.0020.000
Research integrity0.0050.004
Insufficient payload (model declined to judge)0.1130.016

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.012
GPT teacher head0.240
Teacher spread0.228 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; both teacher heads agree on what is shown here.

Study designBench or experimental
Domainnot available
GenreOther

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2007
Admission routes1
Has abstractyes

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