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Record W4246608004 · doi:10.1002/047084289x.rn01695

Dibenzothiophene

2014· reference-entry· en· W4246608004 on OpenAlexaff
Guillaume Benoît

Bibliographic record

VenueEncyclopedia of Reagents for Organic Synthesis · 2014
Typereference-entry
Languageen
FieldMaterials Science
TopicPhotochromic and Fluorescence Chemistry
Canadian institutionsUniversité de Montréal
Fundersnot available
KeywordsComputer science

Abstract

fetched live from OpenAlex

(Dibenzothiophene) [132-65-0] C12H8S (MW 184.26) InChI = 1S/C12H8S/c1-3-7-11-9(5-1)10-6-2-4-8-12(10)13-11/h1-8H InChIKey = IYYZUPMFVPLQIF-UHFFFAOYSA-N (generally used as a key building block in material chemistry) Alternate Name: DBT; diphenylene sulfide. Physical Data: colorless solid. Solubility: soluble in benzene. Form Supplied in: solid, 98% pure (Aldrich) in glass bottles. Analysis of Reagent Purity: 1H NMR (400 MHz, CDCl3) δ 7.29–7.33 (m, 2H), 7.70–7.73 (m, 1H), 7.99–8.01 (m, 1H); 13C NMR (100 MHz, CDCl3) δ 121.7, 122.9, 124.4, 126.8, 135.6, 139.5; mp = 99–100 °C; bp1= 332–333 °C. Stable under normal storage conditions. Handling, Storage, and Precautions: 2 avoid contact with skin and eyes, may cause respiratory tract irritation. Toxic if swallowed. Preparative Methods: commercially available or it can be prepared by several methods that are outlined below.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.002
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow), Insufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Not applicable · Consensus signal: none
GenreCandidate signal: Other · Consensus signal: Other
Teacher disagreement score0.440
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.002
Meta-epidemiology (narrow)0.0010.001
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0010.000
Research integrity0.0010.000
Insufficient payload (model declined to judge)0.0110.001

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.013
GPT teacher head0.238
Teacher spread0.225 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designNot applicable
Domainnot available
GenreOther

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2014
Admission routes1
Has abstractyes

Explore more

Same venueEncyclopedia of Reagents for Organic SynthesisSame topicPhotochromic and Fluorescence ChemistryFrench-language works237,207