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Record W4248689892 · doi:10.1002/047084289x.rb055.pub2

3-Benzyl-5-(2-hydroxyethyl)-4-methyl-1,3-thiazolium Chloride

2016· reference-entry· en· W4248689892 on OpenAlexaff
Heinrich Kuhlmann, Pouyan Haghshenas, Michel Gravel

Bibliographic record

VenueEncyclopedia of Reagents for Organic Synthesis · 2016
Typereference-entry
Languageen
FieldChemistry
TopicN-Heterocyclic Carbenes in Organic and Inorganic Chemistry
Canadian institutionsUniversity of Saskatchewan
Fundersnot available
KeywordsChemistryChlorideMedicinal chemistryOrganic chemistry

Abstract

fetched live from OpenAlex

[4568-71-2] C13H16ClNOS (MW 269.79) InChI = 1S/C13H16NOS.ClH/c1-11-13(7-8-15)16-10-14(11)9-12-5-3-2-4-6-12;/h2-6,10,15H,7-9H2,1H3;1H/q+1;/p-1 InChIKey = IWSVLBKHBJGMAA-UHFFFAOYSA- (in the presence of bases, catalyst for the preparation of acyloins and benzoins2 from aldehydes, and for addition of aldehydes to electrophilic double bonds3) Physical Data: mp 141–143 °C. Solubility: sol H2O, MeOH, EtOH; slightly sol cold MeCN; insol ether, pentane. Form Supplied in: colorless crystals, widely available. Analysis of Reagent Purity: 1H NMR; mp. Preparative Method: Organic Syntheses procedure.2 Handling, Storage, and Precautions: store dry.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.004
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow), Research integrity, Insufficient payload (model declined to judge)
Consensus categoriesMeta-epidemiology (narrow)
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Not applicable · Consensus signal: Not applicable
GenreCandidate signal: Other · Consensus signal: Other
Teacher disagreement score0.349
Threshold uncertainty score0.999

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.004
Meta-epidemiology (narrow)0.0020.002
Meta-epidemiology (broad)0.0030.001
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0030.001
Research integrity0.0030.001
Insufficient payload (model declined to judge)0.0520.001

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.012
GPT teacher head0.244
Teacher spread0.232 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; both teacher heads agree on what is shown here.

Study designNot applicable
Domainnot available
GenreOther

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2016
Admission routes1
Has abstractyes

Explore more

Same venueEncyclopedia of Reagents for Organic SynthesisSame topicN-Heterocyclic Carbenes in Organic and Inorganic ChemistryFrench-language works237,207