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Record W4249576278 · doi:10.22215/etd/2014-10344

Corrosion Performance of Candidate Materials for Canadian Gen IV Supercritical Water Cooled Reactor

2014· dissertation· en· W4249576278 on OpenAlexaboutno aff
Rainier Garcia Sanchez

Bibliographic record

Venuenot available
Typedissertation
Languageen
FieldEngineering
TopicHigh-Temperature Coating Behaviors
Canadian institutionsnot available
Fundersnot available
KeywordsSupercritical fluidCorrosionMaterials scienceSuperheated steamMicrostructureMetallurgySuperheatingChromiumOxideAlloyPressurized water reactorNuclear engineeringChemistry

Abstract

fetched live from OpenAlex

Nuclear power plants have been an important source of energy in many countries for the last fifty years.The Canadian supercritical water cooled reactors (SCWR), among the Generation IV reactors, are currently being designed in Canada and many other countries.It presents challenges for many scientists and engineers due to the harsh environment in which the reactor must operate and the lack of knowledge of material's performance in this corrosive conditions of high temperature and pressure.This thesis entails the corrosion testing of four candidate materials, two nickel based alloys (IN 625 and A-286) and two stainless steels (AISI 304 and AISI 310), and microstructure evaluation of samples after being exposed to supercritical water (SCW), subcritical water (SubCW), and superheated steam.Samples were ground to 600 grit finish and placed in an autoclave and a superheated steam rig to a maximum of three thousand hours and one thousand hours respectively.Procedures, based on the manufacturer's manuals, were created for the setup and operation of all the equipment.The temperature of all three tests was set to 625 o C with a pressure of 29 MPa (SCW), 8 MPa (subcritical water) or ambient (superheated steam).The surface morphology and composition were analyzed using scanning electron microscope (SEM) imaging and energydispersive X-ray spectroscopy (EDS).Results from this study show a poor corrosion performance, in terms of surface oxide formation and weight change, for A-286 and AISI 304 in all conditions due to their low chromium content.AISI 310 and IN 625, with higher chromium content, exhibit an excellent corrosion resistance in almost all conditions, except for the superheated steam test where oxide spallation may have

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.957
Threshold uncertainty score0.086

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0010.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.007
GPT teacher head0.224
Teacher spread0.217 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations3
Published2014
Admission routes1
Has abstractyes

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