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Record W4251614294 · doi:10.1055/s-2003-40330

Synthetic Analogs of the Lewis<sup>b</sup>-Tetrasaccharideand their Binding to Griffonia Simplicifolia Lectin-PartII<b />

2003· article· en· W4251614294 on OpenAlexfundno aff
Ole Hindsgaul, Vivekanand P. Kamath

Bibliographic record

VenueSynlett · 2003
Typearticle
Languageen
FieldChemistry
TopicCarbohydrate Chemistry and Synthesis
Canadian institutionsnot available
FundersNatural Sciences and Engineering Research Council of Canada
KeywordsTetrasaccharideChemistryGriffonia simplicifoliaLectinStereochemistryResidue (chemistry)Ligand (biochemistry)BiochemistryReceptor

Abstract

fetched live from OpenAlex

The lewis b tetrasaccharide is known to bind to lectin IV of Griffonia simplicifolia. In an effort to prepare superior ligands, we have synthesized analogs of this tetrasaccharide and evaluated their binding to the lectin. This paper (part II in a series of two) describes the synthesis of and binding studies with analogs where the GlcNAc unit (a) has been replaced by simpler mimicking residues that are both flexible and rigid. A simple 1,2-trans cyclohexanediol residue provided a reasonable simplified inhibitor whereas a flexible 1,2-ethanediol replacement led to a completely inactive ligand.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.001
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow), Insufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.028
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.001
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.001
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0010.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0020.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.014
GPT teacher head0.217
Teacher spread0.203 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2003
Admission routes1
Has abstractyes

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