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Record W4252936730 · doi:10.1149/ma2017-02/39/1707

Optimization of Anion Exchange Membranes Derived from Cross-linked Chitosan-Poly (diallyldimethylammonium chloride) for All-solid Electrochemical Capacitors

2017· article· en· W4252936730 on OpenAlexaff
Yanan Wei, Bei Ao, Jinli Qiao, Keryn Lian

Bibliographic record

VenueECS Meeting Abstracts · 2017
Typearticle
Languageen
FieldMaterials Science
TopicSupercapacitor Materials and Fabrication
Canadian institutionsUniversity of Toronto
Fundersnot available
KeywordsElectrochemistryCathodeMaterials scienceChemical engineeringTinCarbon fibersFormateAqueous solutionElectrodeCatalysisChemistryMetallurgyComposite materialPhysical chemistryOrganic chemistry

Abstract

fetched live from OpenAlex

Carbon dioxide can be formed in many ways, especially in combustion, it is one of the most important reasons lead to greenhouse effect and global warming. So many scientists devoted themselves to techniques that can reduce CO2 emissions. Among these promising techniques, electrochemical ways provide a efficient means, as it can convert carbon dioxide into fuels and other useful materials.[1,2] This way has many advantages: (a) the process is controllable by setting the temperature of electrode; (b) the system can take advantage of new energy resources and the production do not contaminate environment; (c) the system is compact and easily operated; (d) the experiment can be operated under normal atmospheric pressure and temperature.[3,4] In this paper, Tin-Cu alloy was deposited on carbon paper by electrodeposition in aqueous solution, which was employed as a cathode for electrochemical reduction of CO2 to formate, and how to obtain big catalytic current density, high efficiency and high production rate of formate were explored and discussed. Tin-Cu alloys with different compositions were characterized by morphology, structure, and composition. The electrochemical behavior of the alloys was measured by EIS and CV analysis. In addition, FE, partial current density (PCD), and concentration of HCOO− on the alloys were investigated and compared with those on Sn and Cu electrodes. References [1] S. Rasul, D.H. Anjum, A. Jedidi, Y. Minenkov, L. Cavallo, K. Takanabe, Angew. Chem. Int. Ed., 54,2146(2015). [2] Q. Lu, J. Rosen, Y. Zhou, G.S. Hutchings, Y.C. Kimmel, J.G. Chen, F. Jiao, Nat. Commun., 5,4242(2014). [3] Q. Shen, Z.F. Chen, X.F. Huang, M.C. Liu, G.H. Zhao, Environ. Sci. Technol., 49,5828(2015). [4] X.Q. Min, M.W. Kanan, J. Am. Chem. Soc., 137, 4701(2015).

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.001
Threshold uncertainty score0.003

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0010.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0010.001
Open science0.0000.000
Research integrity0.0010.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.026
GPT teacher head0.286
Teacher spread0.260 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations2
Published2017
Admission routes1
Has abstractyes

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